Materials Reports 2019, Vol. 33 Issue (z1): 462-465 |
POLYMERS AND POLYMER MATRIX COMPOSITES |
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Effect of Plasma-grafted SBMA Modification on Resistance of Ion Exchange Membrane |
GUAN Wenxue1,2, ZHOU Jian1,2, WANG Sanfan1,2, LI Yanhong1,2
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1 School of Enviroment and Municipal Engineering,Lanzhou Jiaotong University, Lanzhou 730070 2 Engineering Research Center of Ministry of Education on Comprehensive Utilization of Water Resources in Cold and Drought Areas,Lanzhou 730070 |
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Abstract Ion exchange alloy films based on styrene-polyvinyl chloride (PVC) were modified by plasma technology using betaine benzene sulfonate (SBMA) as grafting monomer. The optimum modification conditions were investigated by means of electrochemical workstation, scanning electron microscopy (SEM) and infrared spectroscopy (FTIR). The results showed that the modification effect was the best when the mass fraction of SBMA was 5%, the plasma irradiation intensity was 0.75 W/cm2 and the irradiation time was 10 min. After modification, the film surface was compact and smooth, and the resistance of the film was reduced to less than 3 Ω.
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Published: 05 July 2019
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About author:: Wenxue Guan, a postgraduate student, graduated from Northeast Electric Power University in July 2017 with a bachelor’s degree in engineering. He entered Lanzhou Jiaotong University in September 2017 for a master’s degree under Professor Wang Sanfan. He is engaged in the preparation and characterization of ion exchange membranes and the treatment of wastewater.Jian Zhou, associate professor of Lanzhou Jiaotong University. In 2008, he graduated from Northeast Petroleum University, and in 2011, he graduated from Lanzhou Jiaotong University. In 2018, he graduated from Lanzhou Jiaotong University. Participated in the completion of the "Twelfth Five-Year" National Science and Technology Support Plan 2, participated in the National Natural Fund 1, presided over Lanzhou Jiaotong University Youth Fund 1, won Gansu Province Science and Technology Progress Second Prize 1, Gansu Province Fourth University Students Innovation and Entrepreneurship Competition Second Prize 1. He has published 14 scientific papers, applied for 12 patents (one international patent), authorized 2 invention patents and 7 utility model patents. |
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1 赵西云, 王倩, 石绍渊, 等. 过程工程学报,2011(2),329. 2 徐铜文. 膜科学与技术,2008,28(5),1. 3 Nagarale R K, Gohil G S, Shahi V K. Advances in Colloid & Interface Science,2006,119(2-3),97. 4 苏琬. 离子交换膜表面改性的研究—聚吡咯浸渍改性阳膜.硕士学位论文,兰州交通大学,2017. 5 Xu T. Journal of Membrane Science,2005,263(1-2),1. 6 王保国.膜科学与技术,2010,30(1),1. 7 刘阳, 徐晋勇, 高波,等.机械工程材料,2018,42(9),1. 8 黄全江. 等离子体表面接枝及涂覆改性阳离子交换膜.硕士学位论文,兰州交通大学,2017. 9 黄全江, 南君, 王三反,等. 材料导报:研究篇,2018,32(1),203. 10 Chen S H, Chang Y, Lee K R, et al. Langmuir,2012,28(51),17733. 11 Ogieglo W, Grooth J D, Wormeester H, et al.Thin Solid Films,2013,545(11),320. 12 Zhao Y F, Zhu L P, Yi Z, et al. Journal of Membrane Science,2013,440(Complete),40. 13 Chang Y, Chang W J, Shih Y J, et al. ACS Applied Materials & Interfaces,2011,3(4),1228. 14 Jhong J F, Venault A, Hou C C, et al. ACS Applied Materials & Interfaces,2013,5(14),6732. 15 Xu T W, Li Y, Wu L, et al. Separation & Purification Technology,2008,60(1),73. 16 Karpenko L V, Demina O A, Dvorkina G A, et al.Russian Journal of electrochemistry,2001,37(3),287. 17 Kang M S, Choi Y J, Choi I J, et al. Journal of Membrane Science,2003,216(1-2),39. 18 Bidwell P, Nutricula S. European Polymer Journal,2002,38(9),1907. 19 范永生, 陈晓, 王保国. 膜科学与技术,2011,31(2),14. 20 张国俊, 孟洪, 王三反, 等. 环境化学,2002,21(5),417. 21 王三反, 完颜华. 兰州交通大学学报,2000,19(3),72. |
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