| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Research Progress on Functional Casein-based Composites |
| AN Wen1,2, MA Jianzhong1,2, XU Qunna1,2
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1.National Demonstration Center for Experimental Light Chemistry Engineering Education, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021
2.Shaanxi Research Institute of Agricultural Products Processing Technology, Xi’an 710021 |
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Abstract As a natural protein, casein can be dissolved in both acid and alkali medium. Since the film formed by casein dissolving in ammonia water are resistant to water and spoilage, respectively. So borax and ammonia water are usually used to dissolve casein in industry. However, pristine casein can’t meet the needs of modern industry. Therefore, modification of casein is required. In general, modified casein has the following advantages over unmodified casein: (ⅰ) improved water resistance, (ⅱ) enhanced flexibility of films, (ⅲ) improved microbial stability, (ⅳ) special functions, such as self-cleaning, anti-ultraviolet performance and controlled releasing behaviors.
In the early days, casein was modified by introducing polymer monomers to improve its film water resistance or film-forming properties. Howe-ver, with the increasing demand for functionalized products, researchers attempted employing inorganic nanoparticles to modify casein in order to give the special functionality to casein film recently years. Different methods have been used to introduce various nanoparticles in casein system for special functions.
Up to now, the successful examples of nanoparticle-modified casein involved nano zinc oxide (ZnO), nano titanium dioxide (TiO2) and nano ferric oxide (Fe3O4), which can endow casein matrix with antibacterial, self-cleaning and slow releasing properties. Such as, nano-ZnO was introduced into the caprolactam-modified casein matrix by single in-situ polymerization method to prepare casein-based nano-ZnO composite emulsion, which was applied to leather finishing and showed obvious antibacterial properties. Nano-TiO2 was introduced into the polyacrylate-modified casein system by double in-situ polymerization, and the casein-based nano-TiO2 hybrid emulsion applied to leather could endow the system with self-cleaning performance. Nano-Fe3O4 was also designed as a microcapsule structure and coated on casein micelles. Under the action of external magnetic field, it can be applied to the controlled drug release field to give the system a sustained release function. In addition, graphene oxide (GO), montmorillonite (MMT), etc. could also be introduced into the casein system to offer different special functions, which make it more widely available.
This article summarizes the research progress on modification methods and functional modification of casein-based composites, mainly introduces casein modified by polymer and inorganic nanoparticles. The application of casein products in various industries since 1993 is also described. At the same time, the development trend of modified casein in the future is prospected, which will provide reference for obtaining functio-nalized casein products in various fields.
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Published: 02 July 2019
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| Fund:This work was supported by the National Key Research and Development Program of China (2017YFB0308602), Key Scientific Innovation Research Group of Shaanxi Province (2013KCT-08) and Young Talent Lifts Planning Project of Shaanxi Provincial University Science Association (20180416). |
|
|
| [1] |
Silva J V C, Balakrishnan G, Schmitt C, et al. Food Hydrocolloids,2018,82,258.
|
| [2] |
Gao Z B. In: Tannery industrial wastewater treatment, Chemical Industry Press, China,2001.
|
|
高忠柏.制革工业废水处理,化学工业出版社,2001.
|
| [3] |
Nawamawat K, Sakdapipanich J T, Ho C C, et al. Colloids & Surfaces A Physicochemical & Engineering Aspects,2011,390(1),157.
|
| [4] |
Shen X Q, Lan Y J, Xu X H. West Leather,2009,31(13),30(in Chinese).
|
|
申晓庆,兰云军,许晓红.西部皮革,2009,31(13),30.
|
| [5] |
Dai H, Zhang Z C. Leather Science and Engineering,1998(3),47(in Chinese).
|
|
戴红,张宗才.皮革科学与工程,1998(3),47.
|
| [6] |
Li J, Yu X J. Leather Chemicals,1998(6),19(in Chinese).
|
|
李继,余学军.皮革化工,1998(6),19.
|
| [7] |
Rochette C N, Crassous J J, Drechsler M, et al. Langmuir,2013,29(47),14655.
|
| [8] |
Wu L M, Liao S Q, Qu P, et al. Advanced Materials Research,2014,1052,231.
|
| [9] |
Jiang S J, Zhao X H. International Dairy Journal,2011,21(4),198.
|
| [10] |
Liu J, Lu R R. Food and Fermentation Industries,2008,34(10),49(in Chinese).
|
|
刘娟,卢蓉蓉.食品与发酵工业,2008,34(10),49.
|
| [11] |
Mohan D, Ganga R, Rajadurai S. Journal of Macromolecular Science: Part A-Chemistry,1983,20(2),201.
|
| [12] |
Yang Z S, Sheng K M. Leather and Chemicals,1990(6),6(in Chinese).
|
|
杨宗邃,盛克敏.中国皮革,1990(6),6.
|
| [13] |
Somanathan N. Journal of Applied Polymer Science,1996,62(9),1407.
|
| [14] |
Meng H, Tang L, Zheng W H. Lether Chemicals,2003,20(4),21(in Chinese).
|
|
孟辉,唐丽,郑文慧.皮革化工,2003,20(4),21.
|
| [15] |
Xu W G, Yang W T, Wang X. Lether Chemicals,1997(2),14(in Chinese).
|
|
徐卫国,杨文堂,王新.皮革化工,1997(2),14.
|
| [16] |
Dai H, Zhang Z C. Leather Science and Engineering,1998(3),47(in Chinese).
|
|
戴红,张宗才.皮革科学与工程,1998(3),47.
|
| [17] |
Dong Q Z, Hsieh Y L. Journal of Applied Polymer Science,2000,77,2543.
|
| [18] |
Man D L, Lu M, Huang Y P, et al. Polyurethane Industry,2014(4),27(in Chinese).
|
|
满德龙,卢敏,黄毅萍,等.聚氨酯工业,2014(4),27.
|
| [19] |
Zhang Y X, Ma J Z, Xu Q N. Journal of Shaanxi University of Science & Technology,2017,35(3),42(in Chinese).
|
|
张元霞,马建中,徐群娜.陕西科技大学学报,2017,35(3),42.
|
| [20] |
Lakshminarayana Y, Rami Reddy C, Parthasarathy K, et al. Journal-American Leather Chemists Association,1984,79(10),398.
|
| [21] |
Zhu J M, Li P. Jounal of Polymer Science,2003,41,3346.
|
| [22] |
Fan L H, Tang L, Rong X, et al. Leather Chemicals,2004,21(6),23(in Chinese).
|
|
樊丽辉,唐丽,荣星,等.皮革化工,2004,21(6),23.
|
| [23] |
Raval D K, Narola B N, Patel A J. Journal of Applied Polymer Science,2010,98(2),531.
|
| [24] |
Fan L H, Liu J, Zhou M, et al. Leather Chemicals,2006,23(2),25(in Chinese).
|
|
樊丽辉,刘杰,周明,等.皮革化工,2006,23(2),25.
|
| [25] |
Li Y T, Wang T P, Yang J S. China Leather,2007(7),37(in Chinese).
|
|
李运涛,王廷平,杨军胜.中国皮革,2007(7),37.
|
| [26] |
Ma J Z, Li N, Bao Y. China Plastics,2009(6),54(in Chinese).
|
|
马建中,李娜,鲍艳.中国塑料,2009(6),54.
|
| [27] |
Fan B B, Studies on hydrophobic modified using polyurethane microparticle. Master’s Thesis, Central China Normal University, China,2012(in Chinese).
|
|
范冰冰.以聚氨酯微球改性制备疏水热塑性干酪素的研究.硕士学位论文,华中师范大学,2012.
|
| [28] |
Liu Q, Shen Y D, Fei G Q, et al. Polymer Materials Science & Enginee-ring,2011,27(7),151(in Chinese).
|
|
刘钦,沈一丁,费贵强,等.高分子材料科学与工程,2011,27(7),151.
|
| [29] |
Gan C F, Xu Q N, Zhou J H, et al. China Leather,2013,42(5),37(in Chinese).
|
|
甘长凤,徐群娜,周建华,等.中国皮革,2013,42(5),37.
|
| [30] |
Qiao L H, Ma J Z, Xu Q N, et al. China Leather,2013,42(3),30(in Chinese).
|
|
乔滢寰,马建中,徐群娜,等.中国皮革,2013,42(3),30.
|
| [31] |
Duan J C, Tian X H, Sun J X, et al. China Synthetic Rubber Industry,2017,40(3),167(in Chinese).
|
|
段俊超,田晓慧,孙金煜,等.合成橡胶工业,2017,40(3),167.
|
| [32] |
Wang G G, Liu J, Yang J T, et al. Agricultural Development and Equipments,2017(5),73(in Chinese).
|
|
王刚刚,刘杰,杨继涛,等.农业开发与装备,2017(5),73.
|
| [33] |
Shah K J, Shukla A D, Shah D O, et al. Polymer,2016,97,525.
|
| [34] |
Hojiyev R, Ulcay Y, elik M S. Applied Clay Science,2017,146,548.
|
| [35] |
Shah K J, Mishra M K, Shukla A D, et al. Journal of Colloid & Interface Science,2013,407(10),493.
|
| [36] |
Liao R J, Liu T, Zhang F Z, et al. Transactions of China Electrotechnical Society,2015,30(1),220(in Chinese).
|
|
廖瑞金,刘团,张福州,等.电工技术学报,2015,30(1),220.
|
| [37] |
Xing J, Deng B Y, Liu Q S, et al. China Synthetic Fiber Industry,2014,37(5),6(in Chinese).
|
|
邢剑,邓炳耀,刘庆生,等.合成纤维工业,2014,37(5),6.
|
| [38] |
Liu J, Zhuo Y, Li Q. Ferroelectrics,2018,530,39.
|
| [39] |
Li J, Cai J, Zhong L, et al. Applied Clay Science,2018,77,2598.
|
| [40] |
Alexandre M, Dubois P. Materials Science & Engineering R,2000,28(1),1.
|
| [41] |
Zhang K, Wang L, Wang F, et al. Journal of Applied Polymer Science,2004,91(4),2649.
|
| [42] |
Agag T, Koga T, Takeichi T. Polymer,2001,42,3399.
|
| [43] |
Ge J F, Guo B C, Kang Q D, et al. China Adhesives,2005(8),23(in Chinese).
|
|
葛建芳,郭保春,康齐德,等.中国胶粘剂,2005(8),23.
|
| [44] |
Lin H, Xu S, Wang X, et al. Small,2013,9(15),2585.
|
| [45] |
Yang X, Zhao L Y, Tang J T, et al. Journal of Biomedical Engineering,2014,31(2),462.
|
| [46] |
Feng J. Synthesis and surface modification of core-shell gold nanoparticle and its bioapplication, Master’s Thesis, Southeast University, China,2014(in Chinese).
|
|
冯杰.核壳结构的金纳米颗粒的制备、表面修饰及其在生物医学中的应用.硕士学位论文,东南大学,2014.
|
| [47] |
Liu Y, Guo R. Journal of Colloid and Interface Science,2009,332,265.
|
| [48] |
Castaeda M E, Escosura-Muiz A D, González-Ortiz G, et al. Biosensors and Bioelectronics,2013,40,271.
|
| [49] |
Wu Z, Tan D, Tian K, et al. Journal of Physical Chemistry C,2017,121(29),15784.
|
| [50] |
Sangeetha J, Philip J. Colloids and Surfaces A: Physico-chemical and Engineering Aspects,2012,406,52.
|
| [51] |
Huang J, Wang L Y, Lin R, et al. ACS Applied Materials ＆ Interfaces,2013,5,4632.
|
| [52] |
Xi L, Zhang Y W. Silicone Material,2017,31(1),33(in Chinese).
|
|
席龙,张幼维.有机硅材料,2017,31(1),33.
|
| [53] |
Song N, Yang Y W. Chemical Society Reviews,2015,44(11),3474.
|
| [54] |
Zhang D, Li W, Ma Z. Biosensors & Bioelectronics,2018.
|
| [55] |
Wang X, Wang P, Jiang Y, et al. Composites Science and Technology,2014,104,1.
|
| [56] |
Si Y, Guo Z. Chemistry Letters,2015,44(7),874.
|
| [57] |
Zhang S W. Preparation of polystyrene/silica nanocomposite latex and its nanocomposite materials. Master’s Thesis, Changchun University of Technology, China,2017(in Chinese).
|
|
张申伟.聚苯乙烯/二氧化硅纳米复合乳液的合成及其复合材料的制备.硕士学位论文,北京服装学院,2017.
|
| [58] |
Tian B, Liu S, Wu S, et al. Colloids and Surfaces B: Biointerfaces,2017,154,287.
|
| [59] |
Zheng W, Zhu Y, Na B, et al. Composites Science and Technology,2017,144,178.
|
| [60] |
Hu J, Ma J Z, Deng W J. Materials Letters,2008,62,2931.
|
| [61] |
Xu Q, Ma J, Zhou J, et al. Chemical Engineering Journal,2013,228(28),281.
|
| [62] |
Zhang F, Ma J Z, Xu Q N. In: Abstract of the 30th Annual Academic Meeting of the Chinese Chemical Society-31st Session: Colloid and Interface Chemistry. Hangzhou,2016,pp.1.
|
| [63] |
Mohamad Alosfur F K, Ridha N J, Mhh J, et al. Nanotechnology,2018,29(14),145707.
|
| [64 ] |
Fujishima A, Honda K. Nature,1972,37,238.
|
| [65] |
Ryu J, Kim K Y, Hahn B D, et al. Catalysis Communications,2009,10(5),596.
|
| [66] |
Yu H. Progress in Chemistry,2009,75(13),4653.
|
| [67] |
Liang F, Kelly T L, Luo L B, et al. ACS Applied Materials & Interfaces,2012,4(8),4177.
|
| [68] |
Sharma S D, Saini K K, Kant C, et al. Applied Catalysis B Environmental,2008,84(1),233.
|
| [69] |
Liu T, Cao B, Wang C. New Technology & New Process,2010,93(3),735.
|
| [70] |
Xu Q, Fan Q, Ma J, et al. Progress in Organic Coatings,2016,99,223.
|
| [71] |
Zhao C Y, Xiang W F, Zhang J Q, et al. Micronanoelectronic Technology,2015(12),757(in Chinese).
|
|
赵重阳,相文峰,张家奇,等.微纳电子技术,2015(12),757.
|
| [72] |
Dutta R K, Nenavathu B P, Gangishetty M K, et al. Colloids & Surfaces B Biointerfaces,2012,94(6),143.
|
| [73] |
Chaudhary S, Umar A, Bhasin K K, et al. Materials,2018,11(2),287
|
| [74] |
Ma H, Williams P L, Diamond S A. Environmental Pollution,2013,172,76.
|
| [75] |
Chen X Y, Qian X R. China Pulp & Paper,2010,29(5),30.
|
| [76] |
Li Y, Zhang W, Niu J F, et al. ACS Nano,2012,6(6),5164.
|
| [77] |
Abdulrahman S H, Chandrasekaran K, Seemaisamy S, et al. Journal of Materials Chemistry B,2013,1,5956.
|
| [78] |
Emami-Karvani Z, Chehrazi P. African Journal of Microbiology Research,2011,5,1368.
|
| [79] |
Wang Y N, Ma J Z, Xu Q N, et al. Materials & Design,2017,113,240.
|
| [80] |
Wang Y N. Fabrication and performance of antimicrobial casein-based nano ZnO composite for leather finishing. Master’s Thesis, Shaanxi University of Science and Technology, China,2017(in Chinese).
|
|
王雅楠.抗菌型酪素基纳米ZnO复合皮革涂饰材料的合成与性能研究.硕士学位论文,陕西科技大学,2017.
|
| [81] |
Rao C N, Biswas K, Subrahmanyam K S, et al. Journal of Materials Chemistry,2009,19(17),2457.
|
| [82] |
Wei L F, Zhang W B, Ma J Z, et al. Carbon,2019,149,679.
|
| [83] |
Ying H, Wang Z Y, Guo Z Y, et al. Acta Physico-Chimica Sinica,2011,27(6),1482(in Chinese).
|
|
应红,王志永,郭政铎,等.物理化学学报,2011,27(6),1482.
|
| [84] |
Sun Y, Yang S, Chen Y, et al. Environmental Science & Technology,2015,49(7),4255.
|
| [85] |
Hui L, Lu D, Zhang Z, et al. Journal of Materials Science,2015,50(8),3207.
|
| [86] |
Eda G, Fanchini G, Chhowalla M. Nature Nanotechnology,2008,3(5),270.
|
| [87] |
Qin Y, Xin Z, Dai X, et al. Small,2016,126(4),12522.
|
| [88] |
Hinde R A, Spencer-Booth Y. Journal of Power Sources,2015,278(4),218.
|
| [89] |
Dashairya L, Rout M, Saha P. Advanced Composites & Hybrid Materials,2018,1(1),1.
|
| [90] |
Roya Kabiri, Hassan Namazi. Cellulose,2014,21,3527.
|
| [91] |
Maddinedi S B, Mandal B K, Vankayala R, et al. Spectrochimica Acta Part A: Molecularand Biomolecular Spectroscopy,2014,126,227.
|
| [92] |
Qiu C C, Lyu S H, Dong W, et al. West Leather,2013,35(18),32(in Chinese).
|
|
邱超超,吕生华,董文,等.西部皮革,2013,35(18),32.
|
| [93] |
Xu Q N. Synthesis, structure and properties of casein-based emulsifier-free composite emulsion with core-shell structure. Ph.D. Thesis, Shaanxi University of Science and Technology, China,2018(in Chinese).
|
|
徐群娜.酪素基无皂核壳复合乳液的合成、结构与性能研究.博士学位论文,陕西科技大学,2013.
|
| [94] |
Motoki M, Aso H, Seguro K. Agricultural Biology and Chemistry,1987,51(1),993.
|
| [95] |
Diak O A, Bani-Jaber A, Amro B, et al. Food & Bioproducts Processing,2007,85(3),284.
|
| [96] |
Millar F C, Corrigan O I. Drug Development Communications,2008,17(12),1593.
|
| [97] |
Millar F C, Corrigan O I. International Journal of Pharmaceutics,1993,92(1),97.
|
| [98] |
Wang L D, Du F G, Shi J P, et al. China Adhesives,2006,15(3),48(in Chinese).
|
|
王良东,杜风光,史吉平,等.中国胶粘剂,2006,15(3),48.
|
| [99 ] |
Shi S L. Chemistry and Adhesion,2004(1),45(in Chinese).
|
|
石松林.化学与粘合,2004(1),45.
|
| [100] |
Jiang X Y. Advances in Fine Petrochemicals,2005,28(11),88(in Chinese).
|
|
蒋小友.精细石油化工进展,2005,28(11),88.
|
| [101] |
Niu B, Guang Z Y, Wang A X. China Adhesives,2008,17(5),20(in Chinese).
|
|
牛犇,广忠勇,王爱霞.中国胶粘剂,2008,17(5),20.
|
| [102] |
Zhou X L, Cao C Q. Journal of Qingdao University of Science and Technology (Natural Science Edition),2006,27(6),515(in Chinese).
|
|
周学林,曹长青.青岛科技大学学报(自然科学版),2006,27(6),515.
|
| [103] |
Zeng X J, Xu G. China Adhesives,2002,11(6),25(in Chinese).
|
|
曾小君,徐刚.中国胶粘剂,2002,11(6),25.
|
| [104] |
Zheng M Z. A brief analysis of the painting techniques of balthus—The use of casein tempera. Master’s Thesis, Beijing Institute of Fashion, China,2018(in Chinese).
|
|
郑美子.浅析巴尔蒂斯的绘画技法——干酪素坦培拉的运用.硕士学位论文,北京服装学院,2018.
|
| [105] |
Wang S T, Zhang Q S, Li H B. China Adhesives,2000,9(2),19(in Chinese).
|
|
王世泰,张庆思,李洪宝.中国胶粘剂,2000,9(2),19.
|
| [106] |
Seoane B, Castellanos S, Dikhtiarenko A, et al. Coordination Chemistry Reviews,2016,307,147.
|
| [107] |
Nandasiri M I, Jambovane S R, Mcgrail B P, et al. Coordination Che-mistry Reviews,2016,311,38.
|
| [108] |
Cui Y, Li B, He H, et al. Accounts of Chemical Research,2016,49(3),483.
|
| [109] |
Pyun J, Matyjaszewski K. Macromolecules,2000,33(1),217.
|
| [110] |
Wang W P, Fei M, Jie X X, et al. Polymer Bulletin,2010,65(9),863.
|
| [111] |
Jian W, Qing G, Patrick T M. Macromolecules,2010,43(18),7637.
|
| [112] |
Stefano T, Marinella L. Macromolecules,2005,38(13),5569.
|
| [113] |
Ajaya K N, Douglas A M, Joshua U O. Macromolecules,2006,39(20),7037.
|
| [114] |
Ruben Y K, Henryk J S, Jaco D G, et al. Biomacromolecules,2006,7(1),215.
|
| [115] |
Zhang Q H, He H, Xi K, et al. Macromolecules,2011,44(3),550.
|
| [116] |
Ravanfar R, Celli G B, Abbaspourrad A. ACS Applied Materials & Interfaces,2018,10(6),6046.
|
|
|
|
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2019, Vol. 33 
