INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Research Progress of Cu2ZnSnS4 Prepared by Microwave Method |
SHEN Tao1, CHAI Xianhua2, SUN Shuhong2, ZHU Yan2
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1 Faculty of Information Engineering and Automation, Kunming University of Science and Technology, Kunming 650093 2 Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 |
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Abstract Although second-generation thin-film solar energy represented by copper indium gallium selenide (CIGS) and cadmium telluride (CdTe) has been successfully commercialized.Moreover, the power conversion efficiency(PCE) with CIGS as the absorption layer has exceeded 23%,but, due to the scarcity of the In element, the Cd element is highly toxic, which limits its mass production. Cu2ZnSnS4, CZTS is a kind of direct band gap semiconductor. Because of its suitable band gap width, high light absorption coefficient, non-toxic components and abundant reserves, it is the most potential absorbing layer material in solar cells. At present, PCE with CZTS as the absorption layer has exceeded 12%, and this efficiency is close to the current commercial polycrystalline silicon solar cells. Nowadays, the main preparation method of CZTS powder is a solution reaction represented by solvothermal method, one-pot method and hot injection method. Because these methods require expensive equipment, complicated operation sequence, long reaction time, and easy generation of miscellaneous phases, the production efficiency is seriously restricted. Microwave heating is one of the solution chemical reaction methods, but this method has attracted extensive attention in the field of solar cell material preparation in recent years due to its advantages of fast reaction speed, simple operation, high efficiency, uniform heating, and reduced thermal gradient. The CZTS film prepared by microwave heating has two methods of one-step film formation and two-step film formation. The two-step film formation method refers to first synthesizing the powder of CTZS by microwave, and then dispersing the powder and then obtaining the film by spin coating or other methods. However, CZTS belongs to the quaternary compound, and the small deviation of the stoichiometric ratio makes it easy to produce other heterophases. Therefore, how to reduce and control the formation of the heterophase, and prepare the CZTS nanocrystals with pure phase and controllable morphology, and its application to thin film solar cells is crucial. In recent years, in addition to studying the impact of CZTS on device performance, researchers have been trying to select suitable organic solvents, raw material ratios, reaction times, reaction temperatures and surfactants, and have obtained many excellent results. In the full use of the microwave method, the reaction speed is fast, the operation is simple, the efficiency is high, and the heating uniformity is advantageous, and the device efficiency is greatly improved. At present, the conversion efficiency of solar cells prepared by microwave synthesis of CZTS as the absorption layer material of thin film solar cells has rapidly increased from the initial 0.25% to 4.92%. In this paper, the main methods of preparing CZTS powder and CZTS film by microwave method in recent years are reviewed. The effects of raw material ratio, solvent, reaction temperature, reaction time and surfactant on the morphology, structure and optical properties of the product are summarized. The development prospect of CZTS preparation is prospected, in order to provide reference for the preparation of CZTS-based solar cells with higher conversion efficiency.
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Published: 14 June 2019
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Fund:This work was financially supported by the National Natural Science Foundation of China (61764010, 61671225), Yunnan Applied Basic Research Projects (2018FA034). |
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Qing H M, Zhu Y, Hu Y M, et al. Materials Letters, 2016, 176, 177.2 Talapin D V, Lee J S, Kovalenko M V, et al. Chemical Reviews, 2010, 110, 389.3 Habas S E, Platt H A S, Hest M F A M V, et al. Chemical Reviews, 2010, 110, 6571.4 Jackson P, Hariskos D, Lotter E, et al. Progress in Photovoltaics: Research and Applications, 2011, 19, 894.5 Guchhait A, Dewi H A, Leow S W, et al. ACS Energy Letters, 2017, 2, 807.6 Li Z G, Lui A L K, Lam K H, et al. Inorganic Chemistry, 2014, 53, 10874.7 Li M, Zhou W H, Guo J, et al. The Journal of Physical Chemistry C, 2012, 116, 26507.8 Katagiri H, Jimbo K, Maw W S, et al. Thin Solid Films, 2009, 517, 2455.9 Steinhagen C, Panthani M G, Akhavan V, et al. Journal of the American Chemical Society, 2009, 131, 12554.10 Shi C, Shi G, Chen Z, et al. Materials Letters, 2012, 73, 89.11 Moholkar A V, Shinde S S, Babar A R, et al. Solar Energy, 2011, 85, 1354.12 Tao J, Liu J, Chen L, et al. Green Chemistry, 2016, 18, 550.13 Li J, Wang H, Luo M, et al. Solar Energy Materials & Solar Cells, 2016, 149, 242.14 Zhou X, Meng W, Dong C, et al. RSC Advances, 2015, 5, 90217.15 Zhou Y L, Zhou W H, Li M, et al. The Journal of Physical Chemistry C, 2011, 115, 19632.16 Liu W, Guo B, Mak C, et al. Thin Solid Films, 2013, 535, 39.17 Wu S H, Shih C F, Pan H C, et al. Thin Solid Films, 2013, 544, 19.18 Tanaka K, Moritake N, Uchiki H. Solar Energy Materials & Solar Cells, 2007, 91, 1199.19 Park H, Bae B S, Hwang Y H. Journal of Sol-Gel Science and Technology, 2013, 65, 23.20 Chen D, Zhao Y, Chen Y, et al. ACS Applied Materials Interfaces, 2015, 7, 24403.21 Xia D, Zheng Y, Lei P, et al. Physics Procedia, 2013, 48, 228.22 Shin S W, Han J H, Park C Y, et al. Journal of Alloys and Compounds, 2012, 516, 96.23 Wang W, Shen H, He X. Materials Research Bulletin, 2013, 48, 3140.24 Knutson T R, Hanson P J, Aydilb E S, et al. Chem Commun (Communication), 2014, 50, 5902.25 Long F, Mo S Y, Zeng Y, et al. International Journal of Photoenergy, DOI:10.1155/2014/618789.26 Washington A L, Strouse G F. Chemistry of Materials, 2009, 21, 2770.27 Sun C, Richard D W, Long G, et al. International Journal of Chemical Engineering, DOI:10.1155/2011/545234.28 Mitzi D B, Gunawan O, Todorov T K, et al. Solar Energy Materials and Solar Cells, 2011, 95, 1421.29 Yu K, Carter E A. Chemistry of Materials, 2015, 27, 2920.30 Zhou J, You L, Li S, et al. Materials Letters, 2012, 81, 248.31 Nguyen D C, Ito S, Dung D V A. Journal of Alloys and Compounds, 2015, 632, 676.32 Ma G, Minegishi T, Yokoyama D, et al. Chemical Physics Letters, 2011, 501, 619.33 Qiao Qing. Synthesis and photoelectic properties study of Cu2ZnSn(S,Se)4 thin films. Master's Thesis,Henan University, China, 2015(in Chinese).乔青. 液相法制备铜锌锡硫硒薄膜及其光电性能研究.硕士学位论文, 河南大学, 2015.34 Amaya I, Correa R . Revista De Ingeniería, 2016, 38, 33.35 Lu Kai. Agricultural Science & Technology and Equipment, 2007(1), 61 (in Chinese).卢凯.农业科技与装备, 2007(1), 61.36 Xia Xiang, Chen Zuxing, Tan Jie. Mining and Metallurgy in Hainan, 2001(2), 47 (in Chinese).夏湘, 陈祖兴, 谭杰. 海南矿冶, 2001(2), 47.37 Yang Jin. Construction Machinery & Maintenance, 2006(4), 89 (in Chinese).杨瑾. 工程机械与维修, 2006(4), 89.38 Bo Jiajun, Cheng Xinyao. Vacuum Electronics, 1988(1), 58 (in Chinese).鲍家俊, 程信尧. 真空电子技术, 1988(1), 58.39 Tian Z Q, Jiang S P, Liang Y M, et al. The Journal of Physical Chemistry B, 2006, 110, 5343.40 Pallavkar S, Kim T H, Lin J, et al. Industrial & Engineering Chemistry Research, 2010, 49, 8461.41 Wang K C, Chen P, Tseng C M. Crystengcomm, 2013, 15, 9863.42 Li Xinhao. A study on the nature of microwave accelerated organic reactions. Master's Thesis, Beijing University of Chemical Technology, China, 2016(in Chinese).李昕皓. 微波加速有机反应的本质研究.硕士学位论文, 北京化工大学, 2016.43 Kumar R S, Hong C H, Kim M D. Advanced Powder Technology, 2014, 25, 1554.44 Lin Y H, Das S, Yang C Y, et al. Journal of Alloys and Compounds, 2015, 632, 354.45 Gong Z, Han Q, Li J, et al. Journal of Alloys and Compounds, 2016, 663, 617.46 Ghediya P R, Chaudhuri T K. Journal of Physics D Applied Physics, 2015 48,45510947 Flynn B, Wang W, Chang C H, et al. Physica Status Solidi (a), 2012, 209, 2186.48 Saravana Kumar R, Ryu B D, Chandramohan S, et al. Materials Letters, 2012, 86, 174.49 Shin S W, Han J H, Park C Y, et al. Journal of Alloys and Compounds, 2012, 541, 192.50 Sarswat P K, Free M L. Journal of Crystal Growth, 2013, 372, 87.51 Chen W C, Tunuguntla V, Chiu M H, et al. Solar Energy Materials and Solar Cells, 2017, 161, 416.52 Madiraju V A, Taneja K, Kumar M, et al. Journal of Materials Science: Materials in Electronics, 2015, 27, 3152.53 Wang W, Shen H, He X, et al. Journal of Nanoparticle Research, 2014, 16,2437.54 Kandare S P, Dhole S D, Bhoraskar V N, et al. In: The Dae Solid State Physics Symposium. AIP Publishing LLC, 2016, pp.174.55 Patro B, Vijaylakshmi S, Sharma P. In: The Conference Record of the 2015 on Dae Solid State Physics Symposium. AIP Publishing LLC, 2016, pp.28.56 Pinto A H, Shin S W, Isaac E, et al. Journal of Materials Chemistry 2017, 5, 23179.57 Tao W, Wei A, Zhao Y, et al. Journal of Materials Science: Materials in Electronics, 2016, 28, 3407.58 Wang W, Shen H, Jiang F, et al. Journal of Materials Science: Materials in Electronics, 2012, 24, 1813.59 Ansari M Z,Khare N. In: the International Conference on Condensed Matter & Applied Physics. AIP Publishing LLC, 2016, pp. 1.60 Wang W, Shen H, Yao H, et al. Journal of Materials Science: Materials in Electronics, 2015, 26, 1449.61 Yang X, Xu J, Yang Q, et al. Journal of Nanoparticle Research, 2012, 14, 1.62 Zhao Y, Tao W, Chen X, et al. Journal of Materials Science: Materials in Electronics, 2015, 26, 5645.63 Yan X, Michael E, Komarneni S, et al. Ceramics International, 2014, 40, 1985.64 Long F, Chi S, He J, et al. Journal of Solid State Chemistry, 2015, 229, 228.65 Yang H, Su X, Tang A. Materials Research Bulletin, 2007, 42, 1357.66 Zhao Y, Tao W, Liu J, et al. Materials Letters, 2015, 148, 63.67 Li Q, Weia A X, Tao W K, et al. Chalcogenide Letters, 2017, 14, 465.68 Ghediya P R, Chaudhuri T K. Journal of Materials Science: Materials in Electronics, 2014, 26, 1908.69 Martini T, Chubilleau C, Poncelet O, et al. Solar Energy Materials & Solar Cells, 2016, 144, 657.70 Wang W, Shen H, Wong L H, et al. RSC Advances, 2016, 6, 54049.71 Zhou Z, Zhang P, Lin Y, et al. Nanoscale Research Letters, 2014, 9, 477.72 Guo Q, Hillhouse H W, Agrawal R. Journal of the American Chemical Society, 2009, 131, 11672.
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