二维黑磷物理性质及化学稳定性的研究进展

doi:10.11896/j.issn.1005-023X.2018.07.009

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Abstract Black phosphorus was first successfully synthesized in the bulk form in 1914. After remaining silent for 100 years, the novel 2D-nanomaterial formed by attenuating bulk black phosphorus into the multilayer state, i.e. 2D black phosphorus, was firstly obtained in 2014. This layered 2D semiconductor material consisting of only phosphorus atoms has from then onward been drawing intensive interest in the field of low-dimensional inorganic semiconductor because of its rich variety of special electrical and optical properties such as appropriate tunable direct bandgap, high carrier mobility, high leakage current modulation ratio, relatively high on-off current ratio, good electrical and thermal conductivity and strong in-plane anisotropy. 2D black phosphorus is an intrinsic p-type material with a series of excellent properties, but the production of large-area phosphorene (i.e. monolayer black phosp-horus) film has so far remained unrealized due to the instability of 2D black phosphorus. This article intends to make a review of the research progress on 2D black phosphorus. We here introduce systematically the structure, preparation and properties of 2D black phosphorus, also offer a detailed description of its physical properties (electronic, optical, mechanical, thermal, magnetic) and chemical stability. The paper ends with the rough summary and discussion on the research prospect of this emerging new material with sharp momentum.

Key words： 2D black phosphorus physical properties chemical stability phosphorene

Published: 11 May 2018

CLC number:

O472

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	JIA Lei
	LEI Tianmin

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JIA Lei,LEI Tianmin. Research Progress on Physical Properties and Chemical Stability of Two-dimensional Black Phosphorus[J]. Materials Reports, 2018, 32(7): 1100-1106.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.07.009 OR http://www.mater-rep.com/EN/Y2018/V32/I7/1100

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