ZHU Wenjia1,2, LI Xiaobo1,2, CHEN Liangping1,2, OUYANG Xuemei1,2
1 School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105; 2 Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University, Xiangtan 411105
Abstract: The ternary compound Zn55.24Al18.86Zr25.9 was prepared by equilibrated alloy method and examined by X-ray diffraction, scanning election microscopy (SEM). Crystal structure of the compound was successfully refined by the Rietveld method. The reliability factor for Rietveld refinement is Rp=7.15%,Rwp=9.56%.The compound crystallized in a cubic structure with space group p4/mmm, lattice parameters a=b=4.070 803 Å, c=4.073 669 Å. In the structure, Zr atoms occupied the 1a site, some Zn atoms occupied the 2e site, while the other Zn atoms and Al atoms were in the 1c sites. Finally, the rationality of the obtained structure was verified by theoretical calculation.
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2017, Vol. 31 
