Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (24): 109-113    https://doi.org/10.11896/j.issn.1005-023X.2017.024.022
  材料研究 |
温度、浓度对水/乙醇混合溶剂中壳聚糖溶液黏度的影响
杨 帅,张可可,崔 婧,张大伟
东北林业大学材料科学与工程学院,哈尔滨 150040
Effect of Temperature and Concentration on the Viscosity of Chitosan Solution in Water/Ethanol Mixed Solvent
YANG Shuai, ZHANG Keke, CUI Jing, ZHANG Dawei
Institute of Materials Science and Engineering, Northeast Forestry University, Harbin 150040
下载:  全 文 ( PDF ) ( 652KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 研究了溶解于水/乙醇混合溶剂中的壳聚糖溶液黏度随温度和浓度的变化规律。混合溶剂中,乙醇是壳聚糖的不良溶剂,而水是壳聚糖的良溶剂,将乙醇与水按一定比例混合,再加入1%的乙酸,配制成水/乙醇混合溶剂。实验使用乌氏黏度计测量溶液黏度,通过分析黏度随温度、浓度的变化规律,揭示了混合溶剂对壳聚糖溶液黏度的影响规律。研究发现,壳聚糖溶液黏度随着温度的升高而降低;恒定温度,壳聚糖溶液黏度随浓度的增加而增加。而随着温度的升高,壳聚糖在良溶剂中产生的增比黏度变化率要比其在不良溶剂中高;随着浓度的增加,壳聚糖溶液产生的增比黏度的变化率也相应增加。当浓度极稀时,壳聚糖溶液的(ηsp/C)/C曲线会出现反常现象——体系黏度随着浓度的减小而急剧上升。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
杨 帅
张可可
崔 婧
张大伟
关键词:  壳聚糖  温度  浓度  水/乙醇混合溶剂  黏度    
Abstract: The change low of viscosity of chitosan solution in water/ethanol mixed solvent with the temperature and concentration was investigated. Water with 1% (volume) acetic acid added was used as the good solvent. Ethanol, an organic solvent, was the poor solvent. Different proportion of ethanol volume mixed with water solution was acted as poor solvents which could provide solubility of regular difference, respectively. Ubbelohde viscometer was used as the viscosity measuring instrument. And the change low of viscosity of chitosan solution with temperature and concentration was measured. The experimental results showed that the viscosity of chitosan solution reduced with the increasing of temperature. And it would be increased with the increasing of concentration, following the constant temperature. When chitosan solution was in good solvent, the change rate of specific viscosity was higher than that in poor solvent. With the increasing of concentration, the change rate of specific viscosity was increased correspondingly. In the extremely dilute concentration, the(ηsp/C)/C curve of chitosan solution would appear abnormal phenomenon where the viscosity of chitosan solution increased sharply with the decreasing of concentration.
Key words:  chitosan    temperature    concentration    ethanol-water mixed solvent    viscosity
               出版日期:  2017-12-25      发布日期:  2018-05-08
ZTFLH:  TB324  
基金资助: 中央高校基本科研业务费专项资金(2572017EB06);黑龙江省博士后基金(LBH-Z13010);东北林业大学大学生科研训练项目(KY2015014)
通讯作者:  张大伟:男,1975年生,博士,副教授,主要从事生物质材料及其复合材料的研究 E-mail: zhangdawei@nefu.edu.cn   
作者简介:  杨帅:男,1993年生,硕士研究生,主要从事壳聚糖基生物质材料及其复合材料的研究 E-mail: ys930509@163.com
引用本文:    
杨 帅,张可可,崔 婧,张大伟. 温度、浓度对水/乙醇混合溶剂中壳聚糖溶液黏度的影响[J]. 《材料导报》期刊社, 2017, 31(24): 109-113.
YANG Shuai, ZHANG Keke, CUI Jing, ZHANG Dawei. Effect of Temperature and Concentration on the Viscosity of Chitosan Solution in Water/Ethanol Mixed Solvent. Materials Reports, 2017, 31(24): 109-113.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.024.022  或          http://www.mater-rep.com/CN/Y2017/V31/I24/109
1 Croisier F, Jérme C. Chitosan-based biomaterials for tissue engineering[J]. Eur Polym J, 2013,49(4):780.
2 LogithKumar R, KeshavNarayan A, Dhivya S, et al. A review of chitosan and its derivatives in bone tissue engineering[J]. Carbohyd Polym, 2016,151:172.
3 Islam A, Yasin T, Bano I, et al. Controlled release of aspirin from pH sensitive chitosan/poly (vinyl alcohol) hydrogel[J]. J Appl Polym Sci, 2012,124(5):4184.
4 Dutta P K, Khatua M K, Dutta J, et al. Use of Chitosan-DMAc/LiCl gel as drug carriers[J]. J Chem Sci, 2003,1:93.
5 Usman A, Zia K M, Zuber M, et al. Chitin and chitosan based polyurethanes: A review of recent advances and prospective biomedical applications[J]. Int J Biol Macromol, 2016,86:630.
6 Rafique A, Zia K M, Zuber M, et al. Chitosan functionalized poly(vinyl alcohol) for prospects biomedical and industrial applications: A review[J]. Int J Biol Macromol, 2016,87:142.
7 Tsaih M L, Chen R H. Effect of ionic strength and pH on the diffusion coefficients and conformation of chitosans molecule in solution[J]. J Appl Polym Sci, 2015,73(10):2042.
8 EI-hefian E A, Yahaya A H. Rheological study of chitosan and its blends: An overview[J]. Maejo Int J Sci Technol,2010,4(2):210.
9 Luo Y J, Cheng R S, Tan H M. Relationship between viscosity and concentration of nitrocellulose[J]. Chin J Expl Propell, 1999,18(2):42(in Chinese).
罗运军, 程镕时, 谭惠民. 硝化纤维素在稀溶液中的黏度与浓度的依赖关系[J]. 火炸药学报, 1999,18(2):42.
10Dondos A, Skondras P, Pierri E. Hydrodynamic crossover in two polymer mixtures from viscosity measurements[J]. Makromolekulare Chemie, 1983,184(10):2153.
11De Gennes P G. Scaling concepts in polymer physics[M]. Lthaca: Cornell University Press, 1979.
12钱人元, 曹娣. 用分子间激基缔合物荧光研究聚苯乙烯良溶剂溶液——从稀区到亚浓区和浓区的转变[J]. 中国科学(化学), 1983,13(12):1080.
13Wang W. Dilute solution properties of chitosan[J]. Acta Polymerica Sinica, 1992,1(2):202.
王伟. 壳聚糖稀溶液性质的研究[J]. 高分子学报, 1992,1(2):202.
[1] 杨金祥, 石爽, 姜大川, 李旭, 李鹏廷, 谭毅, 姚玉杰, 池明, 张润德, 张建帅. 多晶硅定向凝固过程中温度对凝固速率的影响[J]. 材料导报, 2019, 33(z1): 28-32.
[2] 白强来, 付佺, 潘成刚, 王林德, 慕朝阳. 高延伸率柔性耐烧蚀涂料拉伸性能分析[J]. 材料导报, 2019, 33(z1): 485-487.
[3] 王宗乾, 杨海伟. pH值对海藻酸钠溶液黏度及体系中氢键的影响规律[J]. 材料导报, 2019, 33(8): 1289-1292.
[4] 廖宜顺, 沈晴, 徐鹏飞, 廖国胜, 钟侚. 粉煤灰对水泥基材料水化过程电阻率的影响研究[J]. 材料导报, 2019, 33(8): 1335-1339.
[5] 王杏娟, 靳贺斌, 朱立光, 朴占龙, 王博, 曲硕. B2O3对CaO-Al2O3-SiO2基连铸保护渣性能及结构的影响[J]. 材料导报, 2019, 33(8): 1395-1400.
[6] 侯艳, 程从前, 赵杰, 冯雪, 李然, 闵小华. 拉应力对2205双相不锈钢临界点蚀温度和点蚀行为的影响[J]. 材料导报, 2019, 33(6): 1022-1026.
[7] 陈志国, 方亮, 吴吉文, 张海筹, 马文静, 白月龙. 半固态挤压高硅铝合金二次加热的微观组织演变[J]. 材料导报, 2019, 33(6): 1006-1010.
[8] 周宏明, 王博益, 李荐, 程名辉. CuO掺杂对钇钡铜氧陶瓷电性能的影响[J]. 材料导报, 2019, 33(2): 220-224.
[9] 产玉飞, 陈长军, 张敏. 金属增材制造过程的在线监测研究综述[J]. 材料导报, 2019, 33(17): 2839-2846.
[10] 卫芳彬, 张雷阳, 王颖, 李洋, 刘岗. 二氧化铈掺杂钛酸铋钠基陶瓷的高储能密度及温度稳定性[J]. 材料导报, 2019, 33(16): 2648-2653.
[11] 向红亮, 刘春育, 邓丽萍, 张伟, 任建斌. 固溶温度对节约型双相不锈钢组织及性能的影响[J]. 材料导报, 2019, 33(16): 2759-2764.
[12] 黄国庆, 白震媛, 陈兆文, 刘琦, 王君. 铀(Ⅵ)在氧化锌修饰聚丙烯腈纤维上的吸附行为[J]. 材料导报, 2019, 33(14): 2436-2443.
[13] 王中平, 杨浩宇, 赵亚婷, 徐玲琳. 不同养护温度下氯化钠对铝酸盐水泥水化的影响[J]. 材料导报, 2019, 33(14): 2343-2347.
[14] 侯芹芹, 江元汝, 甘俊羊, 赵亚娟, 赵彬, 韩彤. 溶剂热法合成La1.9Y0.06Mo2O9∶Eu3+Sm3+荧光粉及其能量传递机理[J]. 材料导报, 2019, 33(12): 1939-1944.
[15] 江旭, 马煜林, 刘越. 回火温度对CB2钢的含硼M23C6相析出及力学性能的影响[J]. 材料导报, 2019, 33(12): 2062-2066.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed