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材料导报  2018, Vol. 32 Issue (23): 4142-4149    https://doi.org/10.11896/j.issn.1005-023X.2018.23.016
  无机非金属及其复合材料 |
氯盐和硫酸盐交互作用下水泥基材料的破坏机理综述
曹园章1, 郭丽萍1, 2, 3, 臧文洁1, 张健1, 薛晓丽1
1 东南大学材料科学与工程学院,南京 211189;
2 江苏省土木工程材料重点实验室,南京 211189;
3 先进土木工程材料协同创新中心,南京 211189
Failure Mechanism of Cement-based Materials Subjected to the Interaction Between Chloride and Sulfate—a Review
CAO Yuanzhang1, GUO Liping1, 2, 3, ZANG Wenjie1, ZHANG Jian1, XUE Xiaoli1
1 School of Materials Science and Engineering, Southeast University, Nanjing 211189;
2 Jiangsu Key Laboratory of Construction Materials, Nanjing 211189;
3 Collaborative Innovation Center for Sustainable Civil Engineering Materials &
Structures, Nanjing 211189;
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摘要 西部盐湖和海洋环境中存在大量的氯盐和硫酸盐,当水泥基材料处于氯盐-硫酸盐环境中,其破坏规律以及破坏机理与单一侵蚀因素作用明显不同,因此有必要探究两种盐在侵蚀过程中所呈现的交互作用。已有文献对氯盐和硫酸盐侵蚀下水泥基材料破坏规律的研究可以分为两部分:硫酸盐存在下氯盐对水泥基的侵蚀、氯盐存在下硫酸盐对水泥基的侵蚀。硫酸盐可以明显降低水化产物的氯离子结合量,因为硫酸根不仅能够分解Friedel盐,而且能先与C3A或AFm反应,抑制Friedel盐的产生。但是,氯离子扩散速率高,可以先于硫酸根离子进入水泥基材料内部与水泥水化产物反应,延缓钙矾石的产生,抑制硫酸盐的侵蚀。两种离子在向材料内部侵蚀过程中相互影响,相互牵制。最后,根据目前的研究,提出几个有意义的思考方向。
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曹园章
郭丽萍
臧文洁
张健
薛晓丽
关键词:  氯盐  硫酸盐  复合盐溶液  交互作用  水泥基材料    
Abstract: There coexist large quantities of chlorides and sulfates in both salt lake and marine environment. The failure mode and mechanism of the cement-based materials under the chloride-sulfate circumstance differ considerably from those subjected to either of the two single substances. Hence it is of great necessity to explore the interactive effect between chloride and sulfate. Previous pertinent research can be classified into two aspects: the action of sulfate with the presence of chloride, and the action of chloride with the presence of sulfate. Sulfates have been found capable of significantly reducing the amount of chloride binding, as the sulfate ions can not only decompose the Friedel's salt, but also react with C3A or AFm to inhibit Friedel's salt formation. On the other hand, chloride ions can penetrate into cement-based materials prior to sulfate ions and react with cement hydration products, retarding the generation of ettringite and mitigating the external sulfate attack. As for the ion attack, the two salts interact with each other and restrict each other. Finally, from the perspectives of the current study, several issues which deserve consideration and further exploration are put forward.
Key words:  chloride    sulfate    compound salts solution    interactive effect    cement-based materials
               出版日期:  2018-12-10      发布日期:  2018-12-20
ZTFLH:  TU528.1  
基金资助: 国家重点研发计划(2015CB655102); 国家自然科学基金(51378113; 51778133); 江苏省“六大人才高峰”B类(JZ-004)
作者简介:  曹园章:男,1991年生,硕士研究生,主要从事混凝土耐久性的研究;郭丽萍:通信作者,女,1979年生,副教授,博士研究生导师,主要从事混凝土耐久性和超高延性水泥基复合材料的研究 E-mail:guoliping619@163.com
引用本文:    
曹园章, 郭丽萍, 臧文洁, 张健, 薛晓丽. 氯盐和硫酸盐交互作用下水泥基材料的破坏机理综述[J]. 材料导报, 2018, 32(23): 4142-4149.
CAO Yuanzhang, GUO Liping, ZANG Wenjie, ZHANG Jian, XUE Xiaoli. Failure Mechanism of Cement-based Materials Subjected to the Interaction Between Chloride and Sulfate—a Review. Materials Reports, 2018, 32(23): 4142-4149.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.23.016  或          http://www.mater-rep.com/CN/Y2018/V32/I23/4142
1 Yu H F.Study on high performace concrete in salt lake: Durability, mechanism and service life perdiction[D].Nanjin: Southeast University,2004(in Chinese).
余红发. 盐湖地区高性能混凝土的耐久性、机理与使用寿命预测方法[D].南京:东南大学,2004.
2 Jin Z Q.Durability and service life prediction of concrete exposed to harsh environment in west of China[D].Nanjin: Southeast University,2006(in Chinese).
金祖权. 西部地区严酷环境下混凝土的耐久性与寿命预测[D].南京:东南大学,2006.
3 Liu Y J.Destruction and eveluation of cement-based materials under sulfate-chloride attack[D].Nanjin: Southeast University,2004(in Chinese).
刘玉静. 水泥基材料在硫酸盐—氯盐侵蚀下的破坏与评价[D].南京:东南大学,2016.
4 Jin Z, Sun W, Zhang Y, et al.Interaction between sulfate and chloride solution attack of concretes with and without fly ash[J].Cement and Concrete Research,2007,37(8):1223.
5 Guerrero A, Goñi S, Allegro V.R. Effect of temperature on the durability of class C fly ash belite cement in simulated radioactive liquid waste: Synergy of chloride and sulphate ions[J].Journal of Hazar-dous Materials,2009,165(1-3):903.
6 Ann K Y, Song H W.Chloride threshold level for corrosion of steel in concrete[J].Corrosion Science,2007,49(11):4113.
7 Vennesland. Critical chloride content in reinforced concrete—A review[J].Cement and Concrete Research,2009,60(8):1122.
8 Matschei T, Lothenbach B, Glasser F P.The AFm phase in Portland cement[J].Cement and Concrete Research,2007,37(2):118.
9 Glasser F P, Kindness A, Stronach S A.Stability and solubility relationships in AFm phases: Part Ⅰ. Chloride, sulfate and hydroxide[J].Cement and Concrete Research,1999,29(6):861.
10 Talero R, Trusilewicz L, Delgado A, et al.Comparative and semi-quantitative XRD analysis of Friedel’s salt originating from pozzolan and Portland cement[J].Construction and Building Materials,2011,25(5):2370.
11 Talero R, Trusilewicz L.Morphological differentiation and crystal growth form of friedel’s salt originated from pozzolan and portland cement[J].Industrial and Engineering Chemistry Research,2012,51(38):12517.
12 Wang Xiaogang, Shi Caijun, He Fuqiang, et al.Chloride binding and its effects on microstructure of cement-based materials[J].Journal of the Chinese Ceramic Society,2013,41(2):187(in Chinese).
王小刚,史才军,何富强,等.氯离子结合及其对水泥基材料微观结构的影响[J].硅酸盐学报,2013,41(2):187.
13 Elakneswaran Y, Nawa T, Kurumisawa K.Electrokinetic potential of hydrated cement in relation to adsorption of chlorides[J].Cement and Concrete Research,2009,39(4):340.
14 Zibara H, Hooton R D, Thomas M D A, et al. Influence of the C/S and C/A ratios of hydration products on the chloride ion binding capacity of lime-SF and lime-MK mixtures[J].Cement and Concrete Research,2008,38(3):422.
15 Gou Mifeng, Guan Xuemao, Sun Qian.Adsorption of chloride ion by calcium silicate hydrate[J].Journal of Building Materials,2015,18(3):363(in Chinese).
勾密峰,管学茂,孙倩.水化硅酸钙对氯离子的吸附[J].建筑材料学报,2015,18(3):363.
16 Hirao H, Yamada K, Takahashi H, et al.Chloride binding of cement estimated by binding isotherms of hydrates[J].Journal of Advanced Concrete Technology,2005,3(1):77.
17 Florea M, Brouwers H.Chloride binding related to hydration pro-ducts: Part Ⅰ: Ordinary portland cement[J].Cement and Concrete Research,2012,42(2):282.
18 Gou Mifeng, Guan Xuemao, Zhang Haibo.Study on chloride bin-ding ability of ettringite[J].Materials Review B: Research Papers,2013,27(5):136(in Chinese).
勾密峰,管学茂,张海波.钙矾石结合氯离子能力的研究[J].材料导报:研究篇,2013,27(5):136.
19 Gou Mifeng, Guan Xuemao, Zhang Haibo.Chloride binding in monosulfoaluminate hydrate[J].Journal of Building Materials,2012,15(6):863(in Chinese).
勾密峰,管学茂,张海波.单硫型水化硫铝酸钙对氯离子的固化作用[J].建筑材料学报,2012,15(6):863.
20 Geng J, Easterbrook D, Li L Y, et al.The stability of bound chlorides in cement paste with sulfate attack[J].Cement and Concrete Research,2015,68:211.
21 Geng jian, Yang Haiming, Mo Liwei. Effect of attack of sodium sulfate solution on the sability of bounded chloride ions[J].Journal of Building Materials,2016,18(6):919(in Chinese).
耿健,杨海明,莫利伟.硫酸钠溶液腐蚀对固化态氯离子稳定性的影响[J].建筑材料学报,2015,18(6):919.
22 Xu J, Zhang C, Jiang L, et al.Releases of bound chlorides from chloride-admixed plain and blended cement pastes subjected to sulfate attacks[J].Construction and Building Materials,2013,45:53.
23 Guo L P, Zhang J, Cao Y Z, et al.A study for compound salts attack on ultra-high performance cement-based materials: The stabilities of chemically synthesized Friedel salt and ettringite in solutions of sulfates and chloride salt[J].Materials Review A: Review Papers,2017,31(12):132(in Chinese).
郭丽萍,张健,曹园章,等.超高性能水泥基材料复合盐侵蚀研究:合成Friedel盐和钙矾石在硫酸盐和氯盐溶液中的稳定性[J].材料导报:研究篇,2017,31(12):132.
24 De Weerdt K, Orsáková D, Geiker M.The impact of sulphate and magnesium on chloride binding in Portland cement paste[J].Cement and Concrete Research,2014,65:30.
25 Kunther W, Lothenbach B, Skibsted J.Influence of the Ca/Si ratio of the C-S-H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure[J].Cement and Concrete Research,2015,69:37.
26 Jin Z Q, Sun W, Zhang Y S, et al.Damage of concrete in sulfate and chloride solution[J].Journal of the Chinese Ceramic Society,2006,34(5):630(in Chinese).
金祖权,孙伟,张云升,等.混凝土在硫酸盐、氯盐溶液中的损伤过程[J].硅酸盐学报,2006,34(5):630.
27 Jin Z Q, Sun W, Zhao T J, et al.Chloride binding in concrete exposed to corrosive solutions[J].Journal of the Chinese Ceramic Society,2009,37(7):1068(in Chinese).
金祖权,孙伟,赵铁军,等.在不同溶液中混凝土对氯离子的固化程度[J].硅酸盐学报,2009,37(7):1068.
28 Li P, Yang D Y, Yu J B, et al.Influence of sulfate concentration and strength grade of concrete on chloride binding capacity[J].Concrete,2014(8):23(in Chinese).
李鹏,杨鼎宜,俞君宝,等.硫酸盐环境与水灰比对混凝土氯离子结合能力的影响[J].混凝土,2014(8):23.
29 Tang L.Engineering expression of the ClinConc model for prediction of free and total chloride ingress in submerged marine concrete[J].Cement and Concrete Research,2008,38(8-9):1092.
30 Johannesson B, Yamada K, Nilsson L O, et al.Multi-species ionic diffusion in concrete with account to interaction between ions in the pore solution and the cement hydrates[J].Materials and Structures,2007,40(7):651.
31 Stroh J, Meng B, Emmerling F.Deterioration of hardened cement paste under combined sulphate-chloride attack investigated by synchrotron XRD[J].Solid State Sciences,2016,56:29.
32 Maes M, Mittermayr F, Belie N D.The influence of sodium and magnesium sulphate on the penetration of chlorides in mortar[J].Materials and Structures,2017,50(2):153.
33 Loser R, Lothenbach B, Leemann A, et al.Chloride resistance of concrete and its binding capacity—Comparison between experimental results and thermodynamic modeling[J].Cement & Concrete Composites,2010,32(1):34.
34 Chen X B, Tang M X, Ma K L.Underground concrete structure exposure to sulfate and chloride invading environment[J].Journal of Central South University (Science and Technology),2012,43(7):2803(in Chinese).
陈晓斌,唐孟雄,马昆林.地下混凝土结构硫酸盐及氯盐侵蚀的耐久性实验[J].中南大学学报(自然科学版),2012,43(7):2803.
35 Ma X C, Yi B, Lin D Y, et al.Numerical simulate of transport process of chloride on concrete under the action of sulfate[J].Corrosion and Protection,2014,35(9):880(in Chinese).
马行驰,易博,林德源,等.硫酸盐作用下混凝土中氯离子传输的数值模拟[J].腐蚀与防护,2014,35(9):880.
36 Tian B, Cohen M D.Does gypsum formation during sulfate attack on concrete lead to expansion?[J].Cement and Concrete Research,2000,30(1):117.
37 Rozière E, Loukili A, Hachem R E, et al.Durability of concrete exposed to leaching and external sulphate attacks[J].Cement and Concrete Research,2009,39(12):1188.
38 Santhanam M, Cohen M D, Olek J.Effects of gypsum formation on the performance of cement mortars during external sulfate attack[J].Cement and Concrete Research,2003,33(3):325.
39 Schmidt T, Lothenbach B, Romer M, et al.Physical and microstructural aspects of sulfate attack on ordinary and limestone blended Portland cements[J].Cement and Concrete Research,2009,39(12):1111.
40 Kunther W, Lothenbach B, Scrivener K.Influence of bicarbonate ions on the deterioration of mortar bars in sulfate solutions[J].Cement and Concrete Research,2013,44(1):77.
41 Maes M, Belie N D.Resistance of concrete and mortar against combined attack of chloride and sodium sulphate[J].Cement and Concrete Composites,2014,53(10):59.
42 Mavropoulou N, Katsiotis N, Giannakopoulos J, et al.Durability evaluation of cement exposed to combined action of chloride and sulphate ions at elevated temperature: The role of limestone filler[J].Construction and Building Materials,2016,124:558.
43 Yao W Y, Jin Z Q, Gao S, et al.Influence of temperature and chloride on chemical corrosion of concrete in sulphate[J].Journal of Shenyang University of Technology,2015,37(4):475(in Chinese).
姚维益,金祖权,高嵩,等.温度和氯盐对混凝土硫酸盐化学腐蚀的影响[J].沈阳工业大学学报,2015,37(4):475.
44 Abdalkader A H M, Lynsdale C J, Cripps J C. The effect of chloride on cement mortar subjected to sulfate exposure at low temperature[J].Construction and Building Materials,2015,78:102.
45 Sotiriadis K, Nikolopoulou E, Tsivilis S.Sulfate resistance of limestone cement concrete exposed to combined chloride and sulfate environment at low temperature[J].Cement and Concrete Composites,2012,34(8):903.
46 Zhang M, Chen J, Lv Y, et al.Study on the expansion of concrete under attack of sulfate and sulfate-chloride ions[J].Construction and Building Materials,2013,39(1):26.
47 Damidot D, Lothenbach B, Herfort D, et al.Thermodynamics and cement science[J].Cement and Concrete Research,2011,41(7):679.
48 Balonis M, Lothenbach B, Le Saout G, et al.Impact of chloride on the mineralogy of hydrated Portland cement systems[J].Cement and Concrete Research,2010,40(7):1009.
49 Pourchet S, Regnaud L, Perez J P, et al.Early C3A hydration in the presence of different kinds of calcium sulfate[J].Cement and Concrete Research,2009,39(11):989.
50 Yoon S, Ha J, Chae S, et al.Phase changes of monosulfoaluminate in NaCl aqueous solution[J].Materials,2016,9(5):401.
51 Mesbah A, François M, Cau-Dit-Coumes C, et al. Crystal structure of Kuzel’s salt 3CaO·Al2O3·1/2CaSO4· 1/2CaCl2·11H2O determined by synchrotron powder diffraction[J].Cement and Concrete Research,2011,41(5):504.
52 Maes M, Belie N D.Influence of chlorides on magnesium sulphate attack for mortars with Portland cement and slag based binders[J].Construction and Building Materials,2017,155:630.
53 Yu Y, Zhang Y X.Numerical modelling of mechanical deterioration of cement mortar under external sulfate attack[J].Construction and Building Materials,2018,158:490.
54 Birnin-Yauri U A, Glasser F P. Friedel’s salt, Ca2Al(OH)6(Cl,OH)·2H2O: Its solid solutions and their role in chloride binding[J].Cement and Concrete Research,1998,28(12):1713.
55 Chen Y, Gao J, Tang L, et al.Resistance of concrete against combined attack of chloride and sulfate under drying-wetting cycles[J].Construction and Building Materials,2016,106:650.
56 Sotiriadis K, Nikolopoulou E, Tsivilis S, et al.The effect of chlorides on the thaumasite form of sulfate attack of limestone cement concrete containing mineral admixtures at low temperature[J].Construction and Building Materials,2013,43:156.
57 Liu J P, Liu Y J, Shi L, et al.Combined attack of chloride-sulfate on cement-based materials[J].Journal of Building Materials,2016(6):993(in Chinese).
刘加平,刘玉静,石亮,等.氯盐-硫酸盐对水泥基材料的复合侵蚀破坏[J].建筑材料学报,2016(6):993.
58 Liu T, Qin S, Zou D, et al.Experimental investigation on the durability performances of concrete using cathode ray tube glass as fine aggregate under chloride ion penetration or sulfate attack[J].Construction and Building Materials,2018,163:634.
59 Chiker T, Aggoun S, Houari H, et al.Sodium sulfate and alternative combined sulfate/chloride action on ordinary and self-consolidating PLC-based concretes[J].Construction and Building Materials,2016,106:342.
60 Dehwah H.Effect of sulfate concentration and associated cation type on concrete deterioration and morphological changes in cement hydrates[J].Construction and Building Materials,2007,21(1):29.
61 Weerdt K D, Justnes H.The effect of sea water on the phase assemblage of hydrated cement paste[J].Cement and Concrete Compo-sites,2015,55:215.
62 Weerdt K D, Justnes H, Geiker M R.Changes in the phase assemblage of concrete exposed to sea water[J].Cement and Concrete Composites,2013,47(3):53.
63 Ragab A M, Elgammal M A, Hodhod A G, et al.Evaluation of field concrete deterioration under real conditions of seawater attack[J].Construction and Building Materials,2016,119:130.
64 Brown P W, Badger S.The distributions of bound sulfates and chlorides in concrete subjected to mixed NaCl, MgSO4, Na2SO4 attack[J].Cement and Concrete Research,2000,30(10):1535.
65 Tu L Q, Li Z Y, Ye Z K, et al.Influence on chloride binding capability with mineral admixtures[J].Concrete,2009,(10):57(in Chinese).
屠柳青,李遵云,叶志坤,等.矿物掺合料对水泥浆体氯离子结合性能的影响[J].混凝土,2009,(10):57.
66 Lu Y T.Research on chloride binding capacity of concrete and its test method[D].Nanjing: Nanjing University of Aeronautics and Astronautics,2012(in Chinese).
卢一亭. 混凝土氯离子结合能力及其测试方法研究[D].南京:南京航空航天大学,2012.
67 Song Z, Jiang L, Zhang Z, et al.Distance-associated chloride binding capacity of cement paste subjected to natural diffusion[J].Construction and Building Materials,2016,112:925.
68 Liu C, Ma Z C, Liu H Y.An overview on sulfate corrosion of cement concrete[J].Materials Review,2013,27(7):67(in Chinese).
刘超,马忠诚,刘浩云.水泥混凝土硫酸盐侵蚀综述[J].材料导报,2013,27(7):67.
69 Han Y D, Zhang J, Gao Y.Review of sulfate attack concrete[J].Concrete,2011(1):52(in Chinese).
韩宇栋,张君,高原.混凝土抗硫酸盐侵蚀研究评述[J].混凝土,2011(1):52.
70 Thomas M D A, Hooton R D, Scott A, et al. The effect of supplementary cementitious materials on chloride binding in hardened cement paste[J].Cement and Concrete Research,2012,42(1):1.
71 Yuan Q, Shi C, Schutter G D, et al.Chloride binding of cement-based materials subjected to external chloride environment—A review[J].Construction and Building Materials,2009,23(1):1.
72 Glasser F P, Marchand J, Samson E.Durability of concrete—Degradation phenomena involving detrimental chemical reactions[J].Cement and Concrete Research,2008,38(2):226.
73 Villa R V D L, Goñi S, García R, et al. Effect of sea water on cal-cium effective diffusion of ternary cement[J].Advances in Cement Research,2014,26(3):125.
74 Lothenbach B, Nied D, L’hôpital E, et al.Magnesium and calcium silicate hydrates[J].Cement and Concrete Research,2015,77:60.
75 Bernard E, Lothenbach B, Goff F L, et al.Effect of magnesium on calcium silicate hydrate (C-S-H)[J].Cement and Concrete Research,2017,97:61.
76 Zhu Q, Jiang L, Chen Y, et al.Effect of chloride salt type on chloride binding behavior of concrete[J].Construction and Building Materials,2012,37(37):512.
77 De Weerdt K, Colombo A, Coppola L, et al.Impact of the associa-ted cation on chloride binding of Portland cement paste[J].Cement and Concrete Research,2015,68:196.
78 Song Z, Jiang L, Liu J, et al.Influence of cation type on diffusion behavior of chloride ions in concrete[J].Construction and Building Materials,2015,99:150.
79 Jiang M F, Lv X J.Research and application progresses of concrete early strength agent[J].Bulletin of the Chinese Ceramic Society,2014,33(10):2527(in Chinese).
姜梅芬,吕宪俊.混凝土早强剂的研究与应用进展[J].硅酸盐通报,2014,33(10):2527.
80 Li Q F.Effects of inorganic salt admixtures on microstructure of hydrated C3S and C3A in cement[D].Harbin: Harbin Institute of Technology,2016(in Chinese).
李琴飞. 无机盐外加剂对水泥C3S和C3A水化产物微观结构影响的研究[D].哈尔滨:哈尔滨工业大学,2016.
81 Li Q, Ge Y, Geng G, et al.CaCl2-accelerated hydration of tricalcium silicate: A STXM study combined with 29Si MAS NMR[J].Journal of Nanomaterials,2015,2015(17):1.
82 Mota B, Matschei T, Scrivener K.The influence of sodium salts and gypsum on alite hydration[J].Cement and Concrete Research,2015,75:53.
83 Pang X, Boul P, Jimenez W C.Isothermal calorimetry study of the effect of chloride accelerators on the hydration kinetics of oil well cement[J].Construction & Building Materials,2015,77(77):260.
84 Deng D H, Liu Z Q, Liu Y H, et al.Research progress on theory of “sulfate salt weathering on concrete”[J].Journal of the Chinese Ceramic Society,2012,40(2):175(in Chinese).
邓德华,刘赞群,刘运华,等.关于“混凝土硫酸盐结晶破坏”理论的研究进展[J].硅酸盐学报,2012,40(2):175.
85 Najjar M F, Nehdi M L, Soliman A M, et al.Damage mechanisms of two-stage concrete exposed to chemical and physical sulfate attack[J].Construction and Building Materials,2017,137:141.
86 Nehdi M L, Suleiman A R, Soliman A M.Investigation of concrete exposed to dual sulfate attack[J].Cement and Concrete Research,2014,64:42.
87 Zhutovsky S, Hooton R D.Experimental study on physical sulfate salt attack[J].Materials and Structures,2017,50(1):54.
88 Bassuoni M T, Rahman M M.Response of concrete to accelerated physical salt attack exposure[J].Cement and Concrete Research,2016,79:395.
89 Liu Z, Deng D, De Schutter G, et al.Chemical sulfate attack performance of partially exposed cement and cement + fly ash paste[J].Construction and Building Materials,2012,28(1):230.
90 Haynes H, O’neill R, Neff M, et al.Salt weathering of concrete by sodium carbonate and sodium chloride[J].ACI Materials Journal,2010,107(3):258.
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