Please wait a minute...
材料导报  2018, Vol. 32 Issue (6): 899-904    https://doi.org/10.11896/j.issn.1005-023X.2018.06.009
  材料研究 |
Cr3C2对45钢表面超音速火焰喷涂制备的Ni基合金涂层热态抗磨损性能的影响
苏义祥1, 2, 张志坚2, 邱晓来3, 刘解放2, 申楠2, 刘世铎2
1 兰州理工大学,省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050;
2 兰州理工大学材料科学与工程学院,兰州 730050;
3 浙江超达阀门集团股份有限公司,温州 325100
Effect of Cr3C2 Addition on Thermal Wear Resistant Performance of High Velocity Oxygen Fuel Sprayed Nickel-based Alloy Coating on 45 Steel Substrate
SU Yixiang1, 2, ZHANG Zhijian2, QIU Xiaolai3, LIU Jiefang2, SHEN Nan2, LIU Shiduo2
1 State Key Laboratory of Adcanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology, Lanzhou 730050;
2 College of Material Science and Engineering,Lanzhou University of Technology, Lanzhou 730050;
3 Zhejiang Chaoda Valves Group, Wenzhou 325100
下载:  全 文 ( PDF ) ( 3466KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 采用JP8000型超音速火焰喷涂设备(HVOF)在45钢基体上制备了不同Cr3C2含量的镍基合金涂层,利用金相显微镜、X射线衍射仪、扫描电子显微镜及能谱仪等仪器对涂层组织进行分析,并测定其硬度;采用CFT-Ⅰ型材料表面性能综合测试仪进行摩擦磨损实验,分别测量在50 ℃、100 ℃、150 ℃、200 ℃、250 ℃、300 ℃温度条件下各涂层的摩擦系数及磨损量。结果表明:当摩擦磨损温度在250 ℃以下时,镍基合金涂层的摩擦系数和磨损量由于氧化物薄膜的产生,呈现出随温度升高而下降的趋势,而温度达到250 ℃及以上时产生了严重的粘着磨损,磨损性能随之降低;在镍基合金中添加一定量的Cr3C2,可生成Cr7C3、CrB等多种硬质相,对涂层起到强化作用,改善了涂层在热态条件下的耐磨损性能;镍基合金中Cr3C2的添加量在37.5%左右时,涂层的综合性能优良。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
苏义祥
张志坚
邱晓来
刘解放
申楠
刘世铎
关键词:  碳化铬  镍基合金  涂层  热态磨损  超音速火焰喷涂    
Abstract: Ni-based alloy coatings with different Cr3C2 content were prepared on the 45 steel substrate by using JP8000 type high velocity oxygen fuel (HVOF) spraying equipment.The microstructure of the coatings was analyzed by means of metallographic microscopy, XRD, SEM and EDS, and its hardness was also measured. The friction and wear tests were carried out by CFT-type material surface performance tester. The friction coefficient and wear rate of the coatings were measured at 50 ℃, 100 ℃, 150 ℃, 200 ℃, 250 ℃ and 300 ℃ respectively.The results showed that the friction coefficient and wear rate of Ni based alloy coating decreased with the increase of temperature due to the formation of oxide films when the temperature was below 250 ℃. If the temperature reached 250 ℃ and above, it produced serious adhesive wear, and the wear performance decreases. When a certain amount of Cr3C2 was added to the nickel base alloy, it could produce Cr7C3, CrB and other hard phases, which played a strengthening role on the coating and caused wear resistance improvement of the coating in hot state. When the content of Cr3C2 was about 37.5%, the comprehensive properties of the coating were excellent.
Key words:  chromium carbide    nickel-based alloy    coating    hot wear    high velocity oxygen fuel spraying
               出版日期:  2018-03-25      发布日期:  2018-03-25
ZTFLH:  TG178  
通讯作者:  张志坚,男,1990年生,硕士,研究方向为特种合金粉末与表面技术 E-mail:18893472993@163.com   
作者简介:  苏义祥:男,1956年生,教授,研究方向为特种合金粉末与表面技术 E-mail:syx2757394@163.com
引用本文:    
苏义祥, 张志坚, 邱晓来, 刘解放, 申楠, 刘世铎. Cr3C2对45钢表面超音速火焰喷涂制备的Ni基合金涂层热态抗磨损性能的影响[J]. 材料导报, 2018, 32(6): 899-904.
SU Yixiang, ZHANG Zhijian, QIU Xiaolai, LIU Jiefang, SHEN Nan, LIU Shiduo. Effect of Cr3C2 Addition on Thermal Wear Resistant Performance of High Velocity Oxygen Fuel Sprayed Nickel-based Alloy Coating on 45 Steel Substrate. Materials Reports, 2018, 32(6): 899-904.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.06.009  或          http://www.mater-rep.com/CN/Y2018/V32/I6/899
1 Wu Chaofeng, Ma Mingxing, Liu Wenjin, et al.Study on laser in situ preparation of composite carbide particle reinforced Fe based composite coating and its wear resistance[J].Acta Metallurgica Sinica 2009,45(8):1013(in Chinese).
吴朝锋,马明星,刘文今,等.激光原位制备复合碳化物颗粒增强铁基复合涂层及其耐磨性的研究[J].金属学报,2009,45(8):1013.
2 Xu Hongyong, Wang Wenquan, Huang Shiming,et al. Microstructures and properties of Ni-based wear resistant layers reinforced by TiC generated from in situ plasma spray welding[J].Acta Metallurgica Sinica, 2016,52(11):1423(in Chinese).
徐红勇,王文权,黄诗铭,等.等离子喷焊原位生成TiC硬质增强镍基耐磨层组织与性能[J].金属学报,2016,52(11):1423.
3 Harsha S, Dwivedi D K,Agarwal A. Influence of CrC addition in Ni-Cr-Si-B flame sprayed coatings on microstructure, microhardness and wear behaviour[J]. The International Journal of Advanced Ma-nufacturing Technology,2008,38:93.
4 Xu Binshi, Tan Jun, Chen Jianmin. Development of science and technology in the field of surface engineering[J].China Surface Engineering,2011, 24(2):1(in Chinese).
徐滨士,谭俊,陈建敏.表面工程领域科学技术发展[J].中国表面工程,2011,24(2):1.
5 Buytoz S, Ulutan M, Islak S, et al. Microstructural and wear cha-racteristics of HVOF sprayed NiCrBSi-SiC composite coating on SAE 1030 steel[J].Arabian Journal for Science and Engineering,2013,38:1481.
6 Ou Xian, Deng Changguang, Wang Richu, et al. Research progress of coating wear performance of supersonic plasma sprayed coatings[J].Materials Review,2013,27(S1):104(in Chinese).
欧献,邓畅光,王日初,等,超音速等离子喷涂涂层耐磨性能研究进展[J].材料导报,2013,27(S1):104.
7 Bolelli G, Berger L M, Börner T, et al. Sliding and abrasive wear behaviour of HVOF- and HVAF-sprayed Cr3C2-NiCr hardmetal coatings[J].Wear,2016,32(50):358.
8 Poirier D,Legoux J G,Lima R S. Engineering HVOF-sprayed Cr3C2-NiCr coatings: The effect of particle morphology and spraying parameters on the microstructure, properties, and high temperature wear performance[J].Journal of Thermal Spray Technology,2013,22(2):280.
9 Zhong Wenhua, Liu Guizhong, Pan Jiezong, et al.Comparison of Ni based CrC and Ni based WC coatings by laser cladding[J].Heat Treatment of Metals, 2013,38(3):39(in Chinese).
钟文华,刘贵仲,潘洁宗,等.激光熔覆镍基碳化铬与镍基碳化钨涂层对比研究[J].金属热处理,2013,38(3):39.
10 Guo Yongmin, Li Xuqiang, Wang Haijun, et al.High temperature friction and wear properties of NiCr-Cr3C2/Mo composite coatings sprayed by supersonic plasma spraying[J].China Surface Enginee-ring,2012,25(5):31(in Chinese).
郭永明,李绪强,王海军,等.超音速等离子喷涂NiCr-Cr3C2/Mo复合涂层的高温摩擦磨损性能[J].中国表面工程,2012,25(5):31.
11 Ye Hui, Guo Ping, Zhang Shan,et al.High temperature oxidation resistance of NiCr and Cr3C2-NiCr coatings by ion spraying[J].Electroplating & Finishing,2016,35(14):765(in Chinese).
叶辉,郭平,张姗,等.离子喷涂NiCr和Cr3C2-NiCr涂层的抗高温氧化性能[J].电镀与涂饰,2016,35(14):765.
12 Li Xuefeng.Effect of chromium content on high temperature oxidation behavior of Ni based alloy coating[J].Surface Technology, 2004,33(6):37(in Chinese).
李学锋. 铬含量对镍基合金涂层高温氧化行为的影响机理[J].表面技术,2004,33(6):37.
13 Niu Shaopeng, Deng Changguang, Zhang Jiefu,et al.High temperature friction and wear properties of chromium carbide based coating for supersonic flame spraying[J].Surface Technology,2012,22(6):10(in Chinese).
牛少鹏,邓畅光,张吉阜,等.超音速火焰喷涂碳化铬基涂层的高温摩擦磨损性能研究[J].表面技术,2012,22(6):10.
14 Xiao Ling, Ding Chunhua, Sun Yanhua,et al.Study on the preparation of high temperature self lubricating coating by induction sintering and its properties[J].Acta Metallurgica Sinica,2011,47(3):327(in Chinese).
肖玲,丁春华,孙岩桦,等.感应烧结制备高温自润滑涂层及其性能研究[J].金属学报,2011,47(3):327.
15 Xu Haifeng, Xiao Jinkun,Zhang Ga, et al.Research progress of thermal spraying NiCrBSi based wear resistant coating[J].Surface Technology,2016,45(2):109(in Chinese).
徐海峰,肖金坤,张嘎,等.热喷涂NiCrBSi基耐磨涂层的研究进展[J].表面技术,2016,45(2):109.
16 Zhou Ping, Zhou Changchi, Tang Xinan. Wear characteristics of Ni based alloy and Ni/WC coating by laser cladding[J].Acta Metallurgica Sinica,2002,38(12):1257(in Chinese).
吴萍,周昌炽,唐西南.激光熔覆镍基合金和Ni/WC涂层的磨损特性[J].金属学报,2002,38(12):1257.
17 He Xiangming, Liu Xiubo,Yang Maosheng, et al. High temperature wear behavior of Ni based composite coatings by laser cladding of austenitic stainless steel[J].Chinese Journal of Lasers,2011,38(9):85(in Chinese).
何祥明,刘秀波,杨茂盛,等.奥氏体不锈钢激光熔覆镍基复合涂层高温磨损行为[J].中国激光,2011,38(9):85.
18 Huang Chunbin,Du Linzhong, Zhang Weigang. Preparation and tribological properties of CaF2 and NiCr/Cr3C2- BaF2 high temperature self lubricating and wear resistant coating[J].Tribology, 2009,29(1):68(in Chinese).
黄传兵,杜令忠,张伟刚.NiCr/Cr3C2-BaF2·CaF2高温自润滑耐磨涂层的制备与摩擦磨损特性[J].摩擦学学报,2009,29(1):68.
19 Josep A P, Miquel P, Sergi M, et al.The influence of heat treatment on tribological and mechanical properties of HVOF sprayed CrC-NiCr coa-tings[J].International Journal of Material Forming,2009,2(1):225.
20 Chen Shufa, He Xiangmin, Yang Maosheng,et al.Friction and wear properties of Ni based self lubrication and wear resistant composite coatings under different loading conditions[J].Transactions of Materials and Heat Treatment,2012,33(11):148(in Chinese).
陈书法,何祥明,杨茂盛,等.不同载荷下镍基自润滑耐磨复合涂层的摩擦磨损性能[J].材料热处理学报,2012,33(11):148.
21 Minev R, Ilieva M, Kettle J, et al. Deposition and focused ion beam milling of anticorrosive CrC coatings on tool steel substrates[J]. The International Journal of Advanced Manufacturing Technology, 2010,47(1):29.
22 Li Zhi, Qu Jingxin, Zhao Zhenye,et al. Change mechanism of wear debris for Ni based alloy coating during sliding wear[J].Lubrication Engineering,2003(3):48(in Chinese).
李志,曲敬信,赵振业,等.镍基合金涂层滑动磨损过程中磨屑的演变机理[J].润滑与密封,2003(3):48.
23 Wang Hongtao, Ji Gangchang, Chen Xiao,et al.Abrasive wear resistance of carbide metal ceramic coatings sprayed by supersonic flame[J].Mate-rials for Mechanical Engineering,2011,35(12):44(in Chinese).
王洪涛,纪岗昌,陈枭,等.超音速火焰喷涂碳化物金属陶瓷涂层的磨粒磨损性能[J].机械工程材料,2011,35(12):44.
24 Li Fangpo, Wang Yinzhen, Wang Wei. Study on the microstructure and properties of Ni coatings by HVOF[J].Materials Review,2006,20(8):155(in Chinese).
李方坡,王引真,王纬.超音速火焰喷涂Ni基涂层组织与性能的研究[J].材料导报,2006,20(8):155.
25 Kireitseu M V. Nanoindentation technique at investigating of aluminum oxide-CrC nanoparticles composite coating[C]∥MRS Online Proceedings Library.Minsk, 2002:740.
26 Liu Xinshou, Su Yixiang, Xu Zhuang, et al. Enhancement effect of copper on thermal wear performance of nickel based alloy[J].Materials Science and Engineering of Powder Metallurgy, 2015, 20(5):705(in Chinese).
刘兴寿,苏义祥,徐壮,等.Cu对镍基合金热态磨损能力的增强作用[J].粉末冶金材料科学与工程,2015,20(5):705.
[1] 范舟, 黄泰愚, 刘建仪. 硫对镍基合金825(100)电子结构影响的密度泛函研究[J]. 材料导报, 2019, 33(z1): 332-336.
[2] 胡厅, 万红, 华叶, 龚瑾瑜, 陈兴宇. 石墨表面TiC梯度涂层的制备及结构调制[J]. 材料导报, 2019, 33(z1): 74-77.
[3] 姜志鹏, 陈小明, 赵坚, 张磊, 伏利, 刘伟. 激光熔覆技术制备非晶涂层的研究进展与展望[J]. 材料导报, 2019, 33(z1): 191-194.
[4] 万晔, 刘晶, 谭丽丽, 陈军修, 东家慧, 杨柯. 镁粉表面钙磷涂层的制备与性能[J]. 材料导报, 2019, 33(z1): 283-287.
[5] 平学龙, 符寒光, 孙淑婷. 激光熔覆制备硬质颗粒增强镍基合金复合涂层的研究进展[J]. 材料导报, 2019, 33(9): 1535-1540.
[6] 郭策安, 赵宗科, 赵爽, 卢凤生, 赵博远, 张健. 电火花沉积AlCoCrFeNi高熵合金涂层的高速摩擦磨损性能[J]. 材料导报, 2019, 33(9): 1462-1465.
[7] 李雪换, 底月兰, 王海斗, 李国禄, 董丽虹, 马懿泽. 基于内聚力模型的热障涂层失效行为研究[J]. 材料导报, 2019, 33(9): 1500-1504.
[8] 郝贠洪, 李洁, 刘永利. 输电塔既有涂层与新涂层受风沙侵蚀的损伤机理[J]. 材料导报, 2019, 33(8): 1389-1394.
[9] 马晓波, 王进卿, 池作和, 张光学, 詹明秀. h-BN基复合陶瓷涂层防锅炉受热面的硫酸盐腐蚀性能[J]. 材料导报, 2019, 33(6): 960-964.
[10] 包鑫, 柏胜强, 吴子华, 吴汀, 顾明, 谢华清. CoSb3基方钴矿热电材料保护涂层研究进展[J]. 材料导报, 2019, 33(5): 784-790.
[11] 陈文龙, 刘敏, 张吉阜, 邓子谦, 肖晓玲, 唐维学. 等离子喷涂-物理气相沉积7YSZ热障涂层高温氧化过程中的阻抗谱分析[J]. 材料导报, 2019, 33(4): 605-606.
[12] 董天顺, 郑晓东, 李国禄, 王海斗, 周秀锴, 李亚龙. 大气等离子喷涂Fe基涂层及其氩弧重熔层的组织与力学性能[J]. 材料导报, 2019, 33(4): 678-683.
[13] 陈枭, 白小波, 王洪涛, 纪岗昌. 超音速火焰喷涂多尺度WC-17Co粉末制备的金属陶瓷涂层的组织结构与性能[J]. 材料导报, 2019, 33(4): 684-688.
[14] 曹聪聪, 李文亚, 杨康, 李成新, 纪纲. 基体硬度和热学性质对冷喷涂TC4钛合金涂层组织和力学性能的影响[J]. 材料导报, 2019, 33(2): 277-282.
[15] 许世鸣, 张小锋, 刘敏, 邓春明, 邓畅光, 牛少鹏. APS制备7YSZ热障涂层镀铝改性的抗氧化性[J]. 材料导报, 2019, 33(2): 283-287.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed