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《材料导报》期刊社  2017, Vol. 31 Issue (23): 182-186    https://doi.org/10.11896/j.issn.1005-023X.2017.023.027
  第一届先进胶凝材料研究与应用学术会议 |
基于灰色关联与二分法的无机矿物聚合物强度特性研究*
王晴, 李天如, 张强, 丁兆洋
沈阳建筑大学材料科学与工程学院,沈阳 110168
Strength Characteristics of Geopolymer Based on Gray Relation and Dichotomy
WANG Qing, LI Tianru, ZHANG Qiang, DING Zhaoyang
School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang 110168
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摘要 采用灰色关联分析法与二分法结合,研究了氧化物组成对无机矿物聚合物强度主导因素的影响。研究发现根据强度主导因素的不同可以将无机矿物聚合物分成两个区域,Ⅰ区CaO含量小于25%(ωCaO<25%),该区强度受活性n(SiO2)/n(Al2O3)主导。Ⅱ区CaO含量大于25%(ωCaO>25%),该区强度受CaO含量的影响更大。分别在两区域内进行强度拟合,Ⅰ区符合二元多项式函数,Ⅱ区符合二元傅里叶函数。在各区域内进行强度拟合,拟合曲面投影图说明水玻璃模数在0.8~1.6时,Ⅰ区使用低模数水玻璃激发较好;当n(CaO)/n(SiO2+Al2O3)<0.3时,无机矿物聚合物强度随着n(SiO2)/n(Al2O3)的增大而增大;当n(CaO)/n(SiO2+Al2O3)>0.3时,开始显现出n(CaO)/n(SiO2+Al2O3)对强度的影响,随着n(SiO2)/n(Al2O3)的增大,强度呈现先增大后减小的趋势;Ⅱ区则是高模数水玻璃激发更好,水玻璃模数小时最高强度区域出现在n(CaO)/n(SiO2+Al2O3)值大的区域,当激发剂模数增大时,最高强度区域n(CaO)/n(SiO2+Al2O3)的值减小。
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王晴
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丁兆洋
关键词:  无机矿物聚合物  强度主导因素  氧化钙含量  氧化硅/氧化铝物质的量比  氧化钙/(氧化硅+氧化铝)物质的量比    
Abstract: The influence of oxide composition on the dominant factors of strength in geopolymer was studied by combining gray relational analysis and dichotomy. It was found that the geopolymer could be divided into two regions according to the dominance factor of strength. In regionⅠ where the CaO content of geopolymer was less than 25%, the strength was dominated by the ratio of activity oxides (n(SiO2)/n(Al2O3)). The other was the regionⅡ. CaO content of geopolymer in this area was more than 25%, and the strength was dominated by CaO content. By performing the strength fitting in these two regions respectively, the results showed that the region Ⅰ was in accordance with the binary polynomial function and the region Ⅱ was conformed to the binary Fourier function.The projection of fitting surface showed that when the modulus of the water glass was selected form 0.8 to 1.6, low modulus water glass had better stimulation effect in regionⅠ.When n(CaO)/n(SiO2+Al2O3) was less than 0.3, the strength of geopolymer increased with the increase of n(SiO2)/n(Al2O3) . But if n(CaO)/n(SiO2+Al2O3) was more than 0.3, the effect of n(CaO)/n (SiO2+Al2O3) on strength began to show up, and with the increase of n(SiO2)/n(Al2O3), the strength increased first and then decreased. However, high modulus water glass had better stimulation effect in regionⅡ. The highest strength region appeared in the region where n(CaO)/n(SiO2+Al2O3) was large, when activated with low modulus water glass.With the increasing modulus of activator, the n(CaO)/n(SiO2+Al2O3) of highest strength region decreased.
Key words:  geopolymer    strength dominant factor    calcium oxide content    silica/alumina molar ratio    calcium oxide/(silica+alumina) molar ratio
               出版日期:  2017-12-10      发布日期:  2018-05-08
ZTFLH:  TU58  
基金资助: *辽宁省自然科学基金(201602626)
通讯作者:  张强:男,1991年生,硕士,助理实验师,主要从事新型碱激发胶凝材料研究 E-mail:863261770@qq.com   
作者简介:  王晴:女,1965年生,硕士,教授,主要从事新型碱激发胶凝材料和高性能混凝土研究 E-mail:wangqingmxy@126.com
引用本文:    
王晴, 李天如, 张强, 丁兆洋. 基于灰色关联与二分法的无机矿物聚合物强度特性研究*[J]. 《材料导报》期刊社, 2017, 31(23): 182-186.
WANG Qing, LI Tianru, ZHANG Qiang, DING Zhaoyang. Strength Characteristics of Geopolymer Based on Gray Relation and Dichotomy. Materials Reports, 2017, 31(23): 182-186.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.023.027  或          http://www.mater-rep.com/CN/Y2017/V31/I23/182
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