Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (21): 123-129    https://doi.org/10.11896/j.issn.1005-023X.2017.021.017
  新材料新技术 |
聚合物/凹凸棒土纳米复合材料的研究进展*
高党鸽1, 2, 张亚红1, 2, 马建中1, 2
1 陕西科技大学轻工科学与工程学院,西安 710021;
2 轻化工程国家级实验教学示范中心陕西科技大学,西安 710021
Research Progress of Polymer/Attapulgite Nanocomposites
GAO Dangge1,2, ZHANG Yahong1,2, MA Jianzhong1,2
1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021;
2 National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science and Technology, Xi’an 710021
下载:  全 文 ( PDF ) ( 1757KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 凹凸棒土是一种天然一维纳米材料,具有无毒、热稳定性好、比表面积大等特性,将其与聚合物复合能够改善聚合物的热稳定性能、物理力学性能等。简述了凹凸棒土的改性方法以及聚合物/凹凸棒土纳米复合材料的制备方法,综述了聚合物/凹凸棒土纳米复合材料在塑料、橡胶、污水处理等领域的研究进展,并对其发展进行了展望。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
高党鸽
张亚红
马建中
关键词:  凹凸棒土  复合材料  改性  应用    
Abstract: Attapulgite (ATP), as a valuable naturally available one-dimensional (1D) nanomaterial, has some excellent pro-perties, such as non-toxicity, good thermal stability, large surface area. The thermal stability and mechanical properties of the polymer can be improved by the combination of the polymer and the attapulgite. In this paper, the attapulgite modification method and the preparation of polymer/attapulgite nanocomposites are introduced, the research progress of attapulgite used in plastic, rubber, waste water treatment are summarized, and the application prospect of polymer/attapulgite composites is proposed.
Key words:  attapulgite    composites    modification    application
               出版日期:  2017-11-10      发布日期:  2018-05-08
ZTFLH:  TB33  
基金资助: *陕西省自然科学基础研究计划面上项目(2016JM2029);陕西科技大学科研团队项目(TD12-03)
作者简介:  高党鸽:女,1982年生,博士,教授,硕士研究生导师,主要从事有机/无机纳米复合材料的合成及性能研究 E-mail:dangge2000@126.com
引用本文:    
高党鸽, 张亚红, 马建中. 聚合物/凹凸棒土纳米复合材料的研究进展*[J]. 《材料导报》期刊社, 2017, 31(21): 123-129.
GAO Dangge, ZHANG Yahong, MA Jianzhong. Research Progress of Polymer/Attapulgite Nanocomposites. Materials Reports, 2017, 31(21): 123-129.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.021.017  或          http://www.mater-rep.com/CN/Y2017/V31/I21/123
1 Chisholm J E. Powder-diffraction patterns and structural models for palygorskite[J]. Canadian Mineralogist, 1992,30(1):61.
2 Bradley W F. The structural scheme of attapulgite[J]. American Mineralogist, 1940,25(6):405.
3 Han Zhiyong, Tang Fenglin, Lu Ling, et al. The effect of organically modified attapulgite clay on the petroleum hydrocarbon adsorption of groundwater[J]. J Lanzhou University of Technology, 2014,40(2):73(in Chinese).
韩志勇, 唐凤琳, 鹿玲, 等. 改性凹凸棒土对地下水中石油烃类吸附的影响[J]. 兰州理工大学学报, 2014,40(2):73.
4 Chen Yu, Zhang Liu, Xu Hang, et al. Preparation and property of superabsorbent resin composited with organic attapulgite and P(AA-co-AM)[J]. China Plastics Ind, 2015,43(1):84(in Chinese).
陈宇, 张柳, 徐航, 等. 有机改性凹凸棒土复合P(AA-co-AM)高吸水性树脂的制备及性能研究[J]. 塑料工业, 2015,43(1):84.
5 Liu X Q, Duan X C, Shen M H, et al. Application of attapulgite clay mineral modified by flame retarder in green building materials[J]. Adv Mater Res, 2011,298:8.
6 Yu Jun, Cao Yunfeng, Pi Chengzhong. The characterization and application in paper of different attapulgite clay layer[J]. Paper Sci Technol, 2016,35(1):48(in Chinese).
郁骏, 曹云峰, 皮成忠. 凹凸棒土不同粘土矿层的表征与造纸应用研究[J]. 造纸科学与技术, 2016,35(1):48.
7 Falayi T, Ntuli F. Removal of heavy metals and neutralisation of acid mine drainage with un-activated attapulgite[J]. J Ind Eng Chem, 2014,20(4):1285.
8 Xiang Yuanqing, Chen Dajun. Study on the drug control release performance of attapulgite/poly(HEMA-PEGMA-MAA) nanocompo-site hydrogel[J]. Chem World, 2011,52(9):534(in Chinese).
向远清, 陈大俊. 凹凸棒土/Poly(HEMA-PEGMA-MAA)纳米复合凝胶体系的药物释放性能初探[J]. 化学世界, 2011,52(9):534.
9 Yuan Huijun, Liu Zuojun, Zhang Xuxia, et al. Effect of attapulgite clay on nutrient content in irrigation-silted soil and wheat growth[J]. J Lanzhou University of Technology, 2008,34(6):82(in Chinese).
袁惠君, 刘左军, 张旭霞, 等. 凹凸棒石粘土对灌淤土养分含量及小麦生长的影响[J]. 兰州理工大学学报, 2008,34(6):82.
10Chen H, Zhang Z, Cai D, et al. Attapulgite with poly (methylene blue) composite film-electrocatalytic determination of ascorbic acid[J]. Solid State Sci, 2012,14(3):362.
11Cai D, Wu Z, Jiang J, et al. A unique technology to transform inorganic nanorods into nano-networks[J]. Nanotechnology, 2009,20(25):255302.
12Zhang J P, Wang Q, Chen H, et al. XRF and nitrogen adsorption studies of acid-activated palygorskite[J]. Clay Miner, 2010,45:5.
13Oliveira R N, Acchar W, Soares G D A, et al. The increase of surface area of a brazilian palygorskite clay activated with sulfuric acid solutions using a factorial design[J]. Mater Res, 2013,16:6.
14Yang H M, Tang A D, Ouyang J, et al. From natural attapulgite to mesoporous materials: Methodology, characterization and structural evolution[J]. J Phys Chem B, 2010,114:4.
15Chen Tianhu, Feng Youliang, Shi Xiaoli. Study on products and structural changes of palygorskite with acid[J]. J Chin Ceram Soc, 2003,31(10):959(in Chinese).
陈天虎, 冯有亮, 史晓莉. 凹凸棒石与酸反应产物和结构演化的研究[J]. 硅酸盐学报, 2003,31(10):959.
16Chen Tianhu, Wang Jian, Qing Chensong. Effect of heat treatment on structure, morphology and surface properties of palygorskite[J]. J Chin Ceram Soc, 2006,34(11):1406(in Chinese).
陈天虎, 王健, 庆承松. 热处理对凹凸棒石结构、形貌和表面性质的影响[J]. 硅酸盐学报, 2006,34(11):1406.
17Darvishi Z, Morsali A. Sonochemical preparation of palygorskite nanoparticles[J]. Appl Clay Sci, 2011,51(1):51.
18Huo C, Yang H. Synthesis and characterization of ZnO/palygorskite[J]. Appl Clay Sci, 2010,50(3):362.
19Liu Y, Liu P, Su Z, et al. Attapulgite-Fe3O4 magnetic nanoparticles via co-precipitation technique[J]. Appl Surf Sci, 2008, 255(5): 2020.
20Zhao D, Zhou J, Liu N. Surface characteristics and photoactivity of silver-modified palygorskite clays coated with nanosized titanium dioxide particles[J]. Mater Charact, 2007,58(3):249.
21Zhu L X, Liu P, Wang A Q, et al. High clay-content attapulgite/poly(acrylic acid) nanocomposite hydrogel via surface-initiated redox radical polymerization with modified attapulgite nanorods as initiator and cross-linker[J]. Ind Eng Chem Res, 2014,53(5):2067.
22Lei X P, Liu Y S, Su Z X. Synthesis and characterization of organo-attapulgite/polyaniline-dodecylbenzenesulfonic acid based on emulsion polymerization method[J]. Polym Compos, 2008,29(3):239.
23Xu Jixiang, Kang Yuru, Wang Aiqin, et al. Effect of sodium oleate on physicochemical properties of the modified attapulgite[J]. China Mining Magazine, 2011,20(9):102(in Chinese).
徐继香, 康玉茹, 王爱勤, 等. 油酸钠改性对凹凸棒黏土理化性能的影响[J]. 中国矿业, 2011,20(9):102.
24Tai Y F, Shi C J, Wang C H. Preparation and characterization of anion-cation organopalygorskite for 2-naphthol removal from aqueous solution[J]. J Mol Liquids, 2014,195:116.
25Wang J H, Chen D J. Mechanical properties of natural rubber nanocomposites filled with thermally treated attapulgite[J]. J Nanomater, 2013,2013:4.
26Shi J, Yang X, Wang X, et al. Non-isothermal crystallization kine-tics of nylon 6/attapulgite nanocomposites[J]. Polym Test, 2010,29(5):596.
27Liu Li, Wang Yongren, Zuo Yuping, et al. Mechanical and rheolo-gical properties of attapulgite/poly(lactic acid) nanocomposites[J]. J Chin Ceram Soc, 2012,40(12):1760(in Chinese).
刘莉, 王永仁, 左玉萍, 等. 凹凸棒石/聚乳酸纳米复合材料的力学性能和流变性能[J]. 硅酸盐学报, 2012,40(12):1760.
28Zhang Yue, Xu Jun, Guo Baohua. Microscopic structure and mechanical properties of polylactide/attapulgite nanocomposites[J]. Acta Polym Sin, 2012(1): 83(in Chinese).
章越, 徐军, 郭宝华. 聚乳酸/凹凸棒土纳米复合材料的结构与性能[J]. 高分子学报, 2012(1): 83.
29Wang Yutang, Tang Songchao, Li Yuan, et al. Preparation and properties of attapulgite/ethylene-propylene-diene rubber nanocomposites[J]. China Synth Rubber Ind, 2016,39(1):15(in Chinese).
王钰涛, 唐颂超, 李远, 等. 凹凸棒土/三元乙丙橡胶纳米复合材料的制备与性能[J]. 合成橡胶工业, 2016,39(1):15.
30Zhu L X, Guo J S, Liu P. Effects of length and organic modification of attapulgite nanorods on attapulgite/polystyrene nanocomposite via in-situ radical bulk polymerization[J]. Appl Clay Sci, 2016,119:9.
31Hu Sheng, Yang Mei, Tian Dating, et al. Influence of different preparation methods on the properties of attapulgite/natural rubber composites[J]. Non-Metallic Mines, 2011,34(5):38(in Chinese).
胡盛, 杨眉, 田大听, 等. 不同制备方法对凹凸棒石/天然橡胶复合材料性能的影响[J]. 非金属矿, 2011,34(5):38.
32Hu Sheng, Yang Mei, Shen Shangyue, et al. Modification of attapulgite and its application in natural rubber[J]. J Chin Ceram Soc, 2008,36(6):858(in Chinese).
胡盛, 杨眉, 沈上越, 等. 凹凸棒石的改性及其在天然橡胶中的应用[J]. 硅酸盐学报, 2008,36(6):858.
33Huang Zhaoge, Li Fangzhou, Liu Pingping, et al. Influence of different silane coupling agents on properties of PP/ATP composites[J]. Plastics Sci Technol, 2016,44(7):51(in Chinese).
黄兆阁, 李方舟, 刘平平, 等. 不同硅烷偶联剂对聚丙烯/凹凸棒土复合材料性能的影响[J]. 塑料科技, 2016,44(7):51.
34Zhou Gang, Yan Licheng, Zhang Chi, et al. Preparation and properties of polypropylene/attapulgite composites[J]. Chin J Colloid Polym, 2011,29(4):177(in Chinese).
周刚, 闫礼成, 张弛, 等. 聚丙烯/凹凸棒土复合材料的制备与性能研究[J]. 胶体与聚合物, 2011,29(4):177.
35Wang L, Sheng J. Preparation and properties of polypropylene/org-attapulgite nanocomposites[J]. Polymer, 2005,46(16):6243.
36Gu Fei, Ren Qiang, Li Jinchun. Intumescent flame retardant and attapulgite synergistic flame-retardant polypropylene[J]. Modern Plastics Process Appl, 2013,25(4):29(in Chinese).
顾飞, 任强, 李锦春. 凹凸棒土协同膨胀型阻燃剂阻燃聚丙烯的研究[J]. 现代塑料加工应用, 2013,25(4):9.
37Shi Jianshe, Zhang Chunxiang, Yang Xujie, et al. Spectroscopicanalysis studies of organic-attapulgite/nylon 6 composites[J]. Spectroscopy Spectral Anal, 2011,31(1):223(in Chinese).
史建设, 张春祥, 杨绪杰, 等. 有机化凹凸棒土/尼龙6复合材料的光谱分析研究[J]. 光谱学与光谱分析, 2011,31(1):223.
38Yang Fuxing, Liu Xiaoheng, Yang Xiaoyan, et al. Study on preparation and properties of PA6/organic attapulgite composites[J]. China Plastics Ind, 2010,38(8):29(in Chinese).
杨福兴, 刘孝恒, 杨小燕, 等. PA6/有机化凹凸棒土复合材料的制备及其性能研究[J]. 塑料工业, 2010,38(8):29.
39Pan B L, Yue Q F, Ren J F, et al. A study on attapulgite reinforced PA6 composites[J]. Mater Proper, 2006,25(3):384.
40Liu P, Du P C, Zhu L X, et al. Attapulgite/polylactide nanocomposites: Effect of polymer brush length[J]. Mater Lett, 2014,117:214.
41Zhuang Wei, Jia Haijun, Wang Zhe, et al. Preparation of nano-attapulgite/polylactide composites by in situ polymerization[J]. Acta Mater Compos Sin, 2010,27(4):45(in Chinese).
庄韦, 贾海军, 王喆, 等. 原位聚合法制备纳米凹凸棒土/聚乳酸复合材料[J]. 复合材料学报, 2010,27(4):45.
42Yin H, Chen H F, Chen D J. Morphology and mechanical properties of polyacrylonitrile/attapulgite nanocomposite[J]. J Mater Sci, 2010,45(9):2372.
43Wu Wei, Zhu Songwei, Wang Qin, et al. Effect of modified attapulgite on the extraction of plasticizers in flexible poly(vinyl chloride)[J]. China Plastics, 2016,30(1):28(in Chinese).
吴唯, 朱送伟, 王芹, 等. 改性凹凸棒土对软质聚氯乙烯中增塑剂抽出性的影响[J]. 中国塑料, 2016,30(1):28.
44Duan Huizheng, Sun Meng, Liu Jinchun. Study on elastic properties of attapulgite clay filled polyurethane[J]. Special Purpose Rubber Products, 2014,35(4):17(in Chinese).
段会正, 孙萌, 刘锦春. 凹凸棒土填充聚氨酯弹性体力学性能的研究[J]. 特种橡胶制品, 2014,35(4):17.
45Muttalib S N A, Othman N. Effect of ball milling parameters on properties of attapulgite filled natural rubber composite[J]. Procedia Chem, 2016,19:9.
46Wang Zhangkai, Xiong Yuzhu, Yuan Ye, et al. Properties of natural rubber syenrgistically reinforced by attapulgite clay and carbon black powders[J]. China Powder Sci Technol, 2015,21(5):40(in Chinese).
王章凯, 熊玉竹, 袁野, 等. 凹凸棒土与炭黑粉体协同补强天然橡胶的性能[J]. 中国粉体技术, 2015,21(5):40.
47Shou Wenjuan, Wan Chaoying, Zhang Yong, et al. Study on the properties of carboxylated styrene butadiene rubber reinforced with modified attapulgite[J]. Special Purpose Rubber Products, 2008,29(2):1(in Chinese).
寿文娟, 万超瑛, 张勇, 等. 改性凹凸棒土补强羧基丁苯橡胶性能的研究[J]. 特种橡胶制品, 2008,29(2):1.
48Chen Hongrui, Zhou Si, Tang Qingguo, et al. Study on reinforcing styrene-butadiene rubber with modified attapulgite[J]. Bull Chin Ceram Soc, 2012,31(2):451(in Chinese).
陈红瑞, 周斯, 汤庆国, 等. 改性凹凸棒土补强丁苯橡胶的研究[J]. 硅酸盐通报, 2012,31(2):451.
49Wang Li, Tang Songchao, Li Yuan, et al. Effects of hydrocarbon chain functional modifiers on ethylene propylene diene rubber/attapulgite composites[J]. Polym Mater Sci Eng, 2016,32(6):32(in Chinese).
王丽, 唐颂超, 李远, 等. 烃链功能改性剂对三元乙丙橡胶/凹凸棒土复合材料性能的影响[J]. 高分子材料科学与工程, 2016,32(6):32.
50刘伟生, 谷正. 充油型丁苯橡胶SBR1712/凹凸棒石纳米复合材料的制备方法: 中国, CN101508801 [P]. 2009-08-19.
51刘伟生, 谷正. 充油型丁腈橡胶/凹凸棒土纳米复合材料的制备方法: 中国, CN102250395A [P]. 2011-11-23.
52Tang Q G, Wang F, Guo H, et al. Effect of coupling agent on surface free energy of organic modified attapulgite (OAT) powders and tensile strength of OAT/ethylene-propylene-diene monomer rubber nanocomposites[J]. Powder Technol, 2015,270:92.
53Liu P, Jiang L P, Zhu L X, et al. Synthesis of covalently crosslinked attapulgite/poly (acrylic acid-co-acrylamide) nanocomposite hydrogels and their evaluation as adsorbent for heavy metal ions[J]. J Ind Eng Chem, 2015,23:188.
54Liu P, Jiang L P, Zhu L X, et al. Attapulgite/poly(acrylic acid) nanocomposite (ATP/PAA) hydrogels with multifunctionalized attapulgite (org-ATP) nanorods as unique cross-linker: Preparation optimization and selective adsorption of Pb(II) ion[J]. ACS Sustai-nable Chem Eng, 2014, 2: 643.
55Shao L, Qiu J H, Liu M Z, et al. Preparation and characterization of attapulgite/polyaniline nanofibers via self-assembling and graft polymerization[J]. Chem Eng J, 2010,161:301.
56Li S, Wei Y, Kong Y, et al. Electrochemical removal of lead ions using paper electrode of polyaniline/attapulgite composites[J]. Synthetic Metals, 2015,199:45.
57Cui H, Qian Y, Li Q, et al. Adsorption of aqueous Hg(Ⅱ) by a polyaniline/attapulgite composite[J]. Chem Eng J, 2012,211-212:216.
[1] 洪起虎, 燕绍九, 陈翔, 李秀辉, 舒小勇, 吴廷光. GO添加量对RGO/Cu复合材料组织与性能的影响[J]. 材料导报, 2019, 33(z1): 62-66.
[2] 丁晓飞, 范同祥. 石墨烯增强铜基复合材料的研究进展[J]. 材料导报, 2019, 33(z1): 67-73.
[3] 张谦. 不同铺层角含孔复合材料板拉伸性能数值模拟[J]. 材料导报, 2019, 33(z1): 145-148.
[4] 岳慧芳, 冯可芹, 庞华, 张瑞谦, 李垣明, 吕亮亮, 赵艳丽, 袁攀. 粉末冶金法烧结制备SiC/Zr耐事故复合材料的研究[J]. 材料导报, 2019, 33(z1): 321-325.
[5] 关文学, 周键, 王三反, 李艳红. 等离子体技术接枝苯磺酸甜菜碱改性对离子交换膜电阻的影响[J]. 材料导报, 2019, 33(z1): 462-465.
[6] 柴凡超, 常树全, 王国辉, 姚初请, 戴耀东. 辐射改性对铅/铜高分子辐射屏蔽材料性能的影响[J]. 材料导报, 2019, 33(z1): 444-447.
[7] 周春波, 张有智, 张岳, 王煊军. 聚乙烯基石墨烯复合多孔球形材料的制备及性能表征[J]. 材料导报, 2019, 33(z1): 453-456.
[8] 裴梓帆, 王雪, 唐寅涵, 段皓然, 崔升. 磁性气凝胶材料的应用研究进展[J]. 材料导报, 2019, 33(z1): 470-475.
[9] 罗继永, 张道海, 田琴, 魏柯, 周密, 杨胜都. 无机纳米粒子协同无卤阻燃聚丙烯的研究进展[J]. 材料导报, 2019, 33(z1): 499-504.
[10] 杨康, 赵为平, 赵立杰, 梁宇, 薛继佳, 梅莉. 固化湿度对复合材料层合板力学性能的影响与分析[J]. 材料导报, 2019, 33(z1): 223-224.
[11] 侯珊, 刘向春. 新型光催化剂钨酸锌的制备及性能改性研究进展[J]. 材料导报, 2019, 33(9): 1541-1549.
[12] 秦小凤, 曹嘉真, 汪小莉, 张贤明, 吕晓书. 纳米零价铁优化体系及其在环境中的应用研究进展[J]. 材料导报, 2019, 33(9): 1550-1557.
[13] 余江滔, 田力康, 王义超, 刘柯柯. 具有超高延性的再生微粉水泥基复合材料的力学性能[J]. 材料导报, 2019, 33(8): 1328-1334.
[14] 李茂源, 卢林, 戴珍, 洪义强, 陈为为, 张玉平, 乔英杰. 玻璃微珠和ZrB2改性石英酚醛复合材料的耐烧蚀性能[J]. 材料导报, 2019, 33(8): 1302-1306.
[15] 王应武, 左孝青, 冉松江, 孔德昊. TiB2含量及T6热处理对原位TiB2/ZL111复合材料显微组织和硬度的影响[J]. 材料导报, 2019, 33(8): 1371-1375.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed