Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (17): 61-67    https://doi.org/10.11896/j.issn.1005-023X.2017.017.009
  材料综述 |
阳离子聚合物乳液的研究进展*
张元霞1,2,3, 马建中1,2,3, 徐群娜1,2,3
1 陕西科技大学轻工科学与工程学院,西安 710021;
2 陕西农产品加工技术研究院,西安 710021;
3 中国轻工业皮革清洁生产重点实验室,西安 710021
Research Advances in Cationic Polymer Emulsions
ZHANG Yuanxia1,2,3, MA Jianzhong1,2,3, XU Qunna1,2,3
1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021;
2 Shaanxi Research Institute of Agricultural Products Processing Technology, Xi’an 710021;
3 Key Laboratory of Leather Cleaner Production, China National Light Industry, Xi’an 710021
下载:  全 文 ( PDF ) ( 1607KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 首先介绍了阳离子聚合物乳液的种类和制备方法,并且对其制备方法的优缺点进行了比较,然后阐述了它在纺织、涂料、造纸、水处理、生物医药等领域的应用,最后对其应用前景进行了展望。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
张元霞
马建中
徐群娜
关键词:  阳离子  聚合物  乳液    
Abstract: The types and preparation methods of cationic polymer emulsion are firstly introduced, and their merits and deme-rits are analyzed and compared. Then the applications of cationic polymer emulsion in the fields of textile, coating, papermaking, water treatment, biological medicine and so forth are elaborated. Finally, the developing tendency of cationic polymer mealsion is proposed.
Key words:  cationic    polymer    emulsion
               出版日期:  2017-09-10      发布日期:  2018-05-07
ZTFLH:  TQ31  
基金资助: 陕西省创新团队资助项目(2013KCT-08);陕西科技大学科研创新团队建设项目(TD12-03);国家自然科学基金(21504049)
通讯作者:  马建中:通讯作者,男,1960年生,教授,博士研究生导师,研究方向为有机-无机纳米复合材料的制备与应用 Tel:029-86168006 E-mail:majz@sust.edu.cn   
作者简介:  张元霞:女,1991年生,硕士研究生,研究方向为功能型酪素基阳离子皮革涂饰剂 E-mail:2373840247@qq.com
引用本文:    
张元霞, 马建中, 徐群娜. 阳离子聚合物乳液的研究进展*[J]. 《材料导报》期刊社, 2017, 31(17): 61-67.
ZHANG Yuanxia, MA Jianzhong, XU Qunna. Research Advances in Cationic Polymer Emulsions. Materials Reports, 2017, 31(17): 61-67.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.017.009  或          http://www.mater-rep.com/CN/Y2017/V31/I17/61
1 Nadia A M, Magdy W S, Ahmed H E, et al. Quaternized N-substituted carboxymethyl chitosan derivatives as antimicrobial agents[J]. Int J Biol Macromol,2013,60:156.
2 Wang D F, Zhao T Q, Yan L Q, et al. Synthesis, characterization and evaluation of dewatering properties of chitosan-grafting DMDAAC flocculants[J]. Int J Biol Macromol,2016,92:761.
3 Liu L X, Ma P C, et al. Immune responses to vaccines delivered by encapsulation into and/or adsorption onto cationic lipid-PLGA hybrid nanoparticles[J]. J Controlled Release,2016,225:230.
4 Diaes B, Pa C F, Downing F B, et al. Aqueous dispersion of polymerized halogen-2-butadienes-1,3 and process of preparing same: US, 2138226[P]. 1937-03-02.
5 Liu Yongxu. Synthesis and application of high-elastic acrylic polymer[D]. Jinan:University of Jinan, 2012.
刘勇旭.高弹性丙烯酸酯聚合物的合成与应用[D].济南:济南大学,2012.
6 Gao D G, Ma J Z, Guo H Q. Synthesis of pH-responsive hydrophobically-modified hydrogels of poly(methacrylic acid-co-diallylammo-nium salt) in aqueous solution[J]. New J Chem,2010,34:2034.
7 Gao D G, Chen C, Ma J Z, et al. Preparation, characterization and antibacterial functionalization of cotton fabric using dimethyl diallyl ammonium chloride-allyl glycidyl ether-methacrylic/nano-ZnO composite[J]. Chem Eng J,2014,258:85.
8 Zhao X, Ma H R, Ma J Z, et al. Aerobic biodegradation of polydiallyldimethylammonium chloride-acrylic-acrylamidehydroxyethyl acrylate/ZnO nanocomposite in an activated sludge system[J]. RSC Adv,2015,5:21277.
9 Saif M J, Anwar J, Idrees N, et al. Acrylate copolymers containing benzimidazolium moieties: Synthesis and antimicrobial applications[J]. E-Polymers,2014,14(6):391.
10 Li J C. Effect of cationic monomer on properties of fluorinated acrylate latex[J]. Chin Chem Lett,2012,23(6):736.
11 Zhou J H, et al. Cationic fluorinated polyacrylate emulsifier-free emulsion mediated by poly(2-(dimethylamino) ethyl methacrylate)-b-poly (hexafluorobutyl acrylate) trithiocarbonate via ab initio RAFT emulsion polymerization[J]. Progr Organ Coat,2016,100:86.
12 Shang K X, Shan G R, Pan P J. Stabilizer-free aqueous two-phase copolymerization of acrylamide and cationic monomer: Role of electrostatic interactions in the phase separation, colloid morphology, and stability[J]. Ind Eng Chem Res,2014, 53(38):14664.
13 Woo S, Lee J Y, Choi W. Characterization of ultrahigh-molecular weight cationic polyacrylamide using frit-inlet asymmetrical flow field-flow fractionation and multi-angle light scattering[J]. J Chromatography A,2016,1429:304.
14 Cheng J, et al. Multifunctional cationic polyurethanes designed for non-viral cancer gene therapy[J]. Acta Biomaterialia,2016,30:155.
15 Lu Y S, Larock R C. Soybean oil-based, aqueous cationic polyurethane dispersions: Synthesis and properties[J]. Prog Organ Coat,2010,69(1):31.
16 Xin H, Shen Y D, Li X R. Novel cationic polyurethane-fluorinated acrylic hybrid latexes: Synthesis, characterization and properties[J]. Colloids Surf A: Physicochem Eng Aspects,2011,384:205.
17 Cui Q L, He F, Wang X Y, et al. Gold nanoflower@Gelatin core-shell nanoparticles loaded with conjugated polymer applied for cellular imaging[J]. ACS Appl Mater Interfaces, 2013,5(1):213.
18 Bhowmick S, Scharnweber D, Koul V. Co-cultivation of keratinocyte-human mesenchymal stem cell (hMSC) on sericin loaded electrospun nanofibrous composite scaffold (cationic gelatin/hyaluronan/chondroitin sulfate) stimulates epithelial differentiation in hMSCs: In vitro study[J]. Biomaterials,2016,88:83.
19 Sarika P R, Pavithran A, James N R. Cationized gelatin/gum arabic polyelectrolyte complex: Study of electrostatic interactions[J]. Food Hydrocolloids,2015,49:176.
20 Picchio M L, et al. Waterborne acrylic-casein latexes as eco-friendly binders for coatings[J]. Prog Organ Coat,2015,88:8.
21 Xu Q N, Zhang F, Ma J Z, et al. Facile synthesis of casein-based silica hybrid nano-composite for coatings: Effects of silane coupling agent[J]. Progr Organ Coat,2015,88:1.
22 Holt C, Carver J A, Ecroyd H, et al. Invited review: Caseins and the casein micelle: Their biological functions, structures, and beha-vior in foods[J]. J Dairy Sci,2013, 96(10):6127.
23 Li Huiling, Lei Wanxue, et al. Synthesis, characterization and antibacterial property of quaternary ammonium salt derivatives of casein[J]. J Henan University of Technology:Nat Sci Ed,2010,31(3):54.
李慧灵,雷万学,林钰,等.酪素季铵盐衍生物的合成、表征与抗菌性能[J].河南工业大学学报:自然科学版,2010,31(3):54.
24 徐群娜,马建中,王雅楠,等.一种抗菌封底型阳离子改性酪素皮革涂饰剂的制备方法:中国,201610176201.6[P].2016-03-25.
25 Vandamme D, Foubert I, Meesschaert B. Flocculation of microalgae using cationic starch[J]. J Appl Phycol,2010,22(4):525.
26 Butrim S M, Bil’dyukevich T D, Butrim N S, et al. Preparation and flocculating properties of highly substituted cationic starches of different vegetable origins[J]. Kolloidnyi Zhurnal, 2016,78(3):298.
27 Sirvio J A, Anttila A K, Pirttila A M, et al. Cationic wood cellulose films with high strength and bacterial anti-adhesive properties[J]. Cellulose,2014,21(5):3573.
28 Mohan T, Niegelhell K, Zarth C S P. Triggering protein adsorption on tailored cationic cellulose surfaces[J]. Biomacromolecules,2014,15(11):3931.
29 Li Mingchun, Xu Tao, Xing Meihua. Research progress of antibac-terial activity of chitosan and its derivatives [J]. Chem Ind Eng Prog,2011,30(1):203.
李明春,许涛,辛梅华.壳聚糖及其衍生物的抗菌活性研究进展[J]. 化工进展,2011,30(1):203.
30 Chethan P D, Vishalakshi B, Sathish L. Preparation of substituted quaternized arylfuran chitosan derivatives and their antimicrobial activity[J]. Int J Biol Macromol,2013,59:158.
31 Zou X, Zhao X W, Ye L. Synthesis of cationic chitosan hydrogel and its controlled glucose-responsive drug release behavior[J]. Chem Eng J,2015,273:92.
32 Yan X H, Ji Y X, Li T H. Synthesis of fiber crosslinking cationic latex and its effect on surface properties of paper[J]. Prog Organ Coat,2013,76:11.
33 Yang Qinhuan, et al. Progress of fluorinated acrylate copolymer latexes (Ⅰ): Polymerization techniques and safety of fluorinated acrylate monomers[J]. China Leather,2009,38(9):52.
杨秦欢,张廷有,李正军.含氟丙烯酸酯聚合物乳液研究新进展(Ⅰ)—合成技术和含氟单体的安全性[J].中国皮革,2009,38(9):52.
34 Yan X H, Xu W, Sao R. Synthesis of polymerizable quaternary ammonium emulsifier and properties of its fiber crosslining emulsion[J]. Colloids Surf A: Physicochem Eng Aspects,2014,443:60.
35 Shao Qian, Wang Chengguo, Zheng Heng. Development of seeded emulsion polymerization[J]. Chin Polym Bull,2007(10):57.
邵谦,王成国,郑衡,等.种子乳液聚合的研究进展[J].高分子通报,2007(10):57.
36 Vanderhoff J W, Bradford Ε B, Tarkowski H L. Inverse emulsion polymerization [J]. Adv Chem,1962,34(2):32.
37 Yoon D H, Jang J W, Cheong I W. Synthesis of cationic polyacry-lamide/silica nanocomposites from inverse emulsion polymerization and their flocculation property for papermaking[J]. Colloids Surf A: Physicochem Eng Aspects,2012, 411:18.
38 González G, De la Cal J C, Asua J M. Synthesis of cationic flocculants in continuous reactors[J]. Chem Eng J,2010,162(2):753.
39 Oliveira M A M, Boyer C, Nele M, et al. Synthesis of biodegradable hydrogel nanoparticles for bioapplications using inverse miniemulsion RAFT polymerization[J]. Macromolecules, 2011,44(18):7167.
40 Wei Xin, Zhong Hong. Research progress of inverse emulsion polymerization[J]. Chem Bioeng,2007,24(12):12.
魏鑫,钟宏.反相乳液聚合的研究进展[J]. 化学与生物工程,2007,24(12):12.
41 Shang K X, Shan G R, Pan P J. Unusual soluble-insoluble-soluble phase transition in two-phase copolymerization of acrylamide and an anionic comonomer in a poly(ethylene glycol) aqueous solution[J]. Ind Eng Chem Res,2014,53:10681.
42 Gao D G, Feng J F, Ma J Z. Synthesis of cationic binder through surfactant-free emulsion polymerization for textile pigment applications[J]. Prog Organ Coat,2014,77(11):1834.
43 Li W W, Matyjaszewski K. Cationic surface-active monomers as reactive surfactants for AGET emulsion ATRP of n-Butyl methacrylate[J]. Macromolecules,2011,44(14):5578.
44 Chen Wanming. Research and application of functional cationic polymer emulsion[J]. Guizhou Chem Ind,2003,28(2):21.
陈万明.功能性阳离子聚合物乳液研究及应用[J].贵州化工,2003,28(2):21.
45 Wang C, Li X R, Du B, et al. Effect of cationic monomer on properties of cationic fluorocarbon emulsifier-free emulsion[J]. J Polym Res-Taiwan,2013,20:94.
46 Gao Dangge, Chen Chen, Ma Jianzhong, et al. Preparation, characterization and application of ZnO sol containing quaternary ammo-nium salts[J]. J Sol-gel Sci Technol,2013,65:336.
47 周建华,陈欣,彭颖姗,等.阳离子含氟聚丙烯酸酯无皂乳液的制备方法:中国,201410250163.5[P].2014-06-06.
48 Tang Junling, Wang Xueyan. Application of cationic gelatin protein in cotton fabric scouring and bleaching[J]. J Xi’an Polytechnic University,2015,29(2):146.
唐俊玲,王雪燕.阳离子明胶蛋白在棉织物练漂中的应用[J]. 西安工程大学学报,2015,29(2):146.
49 Tang Junling, Wang Xueyan. Effect of cationic gelatin protein on hydrogen peroxide decomposition rate[J]. Textile Dyeing Finishing J,2016,38(3):51.
唐俊玲,王雪燕.阳离子明胶蛋白助剂对双氧水分解率的影响[J].染整技术,2016,38(3):51.
50 Sangermano M, Tonin M, Yagci Y. Degradable epoxy coatings by photoinitiated cationic copolymerization of bisepoxide with e-caprolactone[J]. Eur Polym J,2010,46(2):254.
51 Luis J Bastarrachea, Julie M Goddard. Antimicrobial coatings with dual cationic and N-halamine character: Characterization and biocidal efficacy[J]. J Agricultural Food Chem,2015,63:4243.
52 Wang Baihui, Wang Xueyan, Han Huimin, et al. Property and application study of positive ion gelation protein derivative size mixture[J]. Cotton Textile Technol,2015,43(4):5.
王百慧,王雪燕,韩惠民,等.阳离子明胶蛋白衍生物浆料性能及应用研究[J].棉织物技术,2015,43(4):5.
53 Wang Y, Fang S J. Preparation and characterization of cationic silicone-acrylic latex surface sizing agent[J]. Prog Organ Coat,2015,88:144.
54 Tseng C L, Chen K H, Su W Y, et al. Cationic gelatin nanoparticles for drug delivery to the ocular surface: In vitro and in vivo evaluation[J]. J Nanomaterials,DOI:10.11551/2013/238351.
55 Chen X M, et al. Enhanced humoral and cell-mediated immune responses generated by cationic polymer-coated PLA microspheres with adsorbed HbsAg[J]. Mol Pharmaceut,2014,11(6):1772.
56 Ren W J, et al. Synthesis and evaluation of a novel cationic konjac glucomannan-based flocculant[J]. Carbohyd Polym,2016,144:238.
57 Fu J N, Qiao R, Zhu L L, et al. Application of a novel cationic starch in enhanced oil recovery and its adsorption properties[J]. Korean J Chem Eng,2013, 30(1):82.
[1] 马攀龙, 张忠厚, 韩琳, 陈荣源. 交联剂和无纺布增强聚丙烯腈凝胶聚合物电解质膜的研究[J]. 材料导报, 2019, 33(z1): 457-461.
[2] 高科, 李万万. 近红外二区光声成像造影剂的研究进展[J]. 材料导报, 2019, 33(z1): 481-484.
[3] 路小彬. 基于嵌段共聚物的硅表面聚合物刷点阵组装[J]. 材料导报, 2019, 33(z1): 505-509.
[4] 刘国军, 张生义, 钟明月, 张桂霞, 王艳, 余大平. BEM含量对MAA-EA-MMA共聚物乳液的pH响应性研究[J]. 材料导报, 2019, 33(8): 1422-1426.
[5] 张默, 王诗彧. 常温制备赤泥-低钙粉煤灰基地聚物的试验和微观研究[J]. 材料导报, 2019, 33(6): 980-985.
[6] 冯妙, 刘燕, 邓会宁, 王子霞. 层层自组装法制备氧化石墨烯复合单价选择性离子交换膜[J]. 材料导报, 2019, 33(6): 1057-1060.
[7] 崔龙辰, 王军军, 黄伟九. 类聚合物碳薄膜的制备及其摩擦学研究进展[J]. 材料导报, 2019, 33(5): 797-804.
[8] 朱继红, 曾碧榕, 罗伟昂, 袁丛辉, 陈凌南, 毛杰, 戴李宗. Fe3O4@P(St-co-OBEG)核壳结构微球负载银/铂纳米粒子复合催化剂的构筑及催化性能[J]. 材料导报, 2019, 33(4): 571-576.
[9] 翟乐, 吉海峰, 姚艳梅, 瞿雄伟. 利用聚丙烯酸正丁酯@聚甲基丙烯酸甲酯核/壳结构聚合物增韧氰酸酯树脂[J]. 材料导报, 2019, 33(4): 705-708.
[10] 魏波,周金堂,姚正军,钱逸,钱崑. 环氧树脂基体的原位增韧技术研究进展[J]. 材料导报, 2019, 33(17): 2976-2988.
[11] 皮茂, 张守村, 魏杰, 李伟达. 采用高内相乳液模板法制备葡萄糖基/麦芽糖基大孔材料及其形貌表征[J]. 材料导报, 2019, 33(16): 2804-2807.
[12] 马骁, 谢雪鹏, 叶雄伟, 何巨鹏, 朱杰. 基于氮气吸附法的钙基地聚合物孔隙结构分形特征[J]. 材料导报, 2019, 33(12): 1989-1994.
[13] 董雨菲, 马建中, 刘超, 鲍艳, 林阳, 吴英柯. SiO2的功能化改性及其与聚合物基体的界面研究进展[J]. 材料导报, 2019, 33(11): 1910-1918.
[14] 韦晶, 韩希思, 张承武, 吴琼, 秦晓飞, 李林, 余昌敏, 黄维. 微小RNA纳米递送体系的构建及其研究进展[J]. 材料导报, 2019, 33(1): 16-26.
[15] 曾祥花, 李战峰, 任静琨, 刘伟鹏, 陈今波, 王向坤, 郝玉英. 基于噻吩-苯非对称单元的DPP类聚合物给体材料的合成及光伏性能[J]. 《材料导报》期刊社, 2018, 32(9): 1423-1426.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed