Abstract: 3D graphene materials not only inherits perfect carbon crystal structure of 2D graphene sheet, but also shows unique structural characteristics, including ultra-low density, high porosity, large specific surface area, and so forth. 3D graphene has become a new star in functional materials field in recent years because of its excellent performance involving electrical, thermal, and adsorption properties. At present, the studies of 3D graphene-based polymer composites or 3D graphene/inorganic nano compo-sites have made a substantial progress. Researchers have realized 3D well-aligned and controlled assembly between graphene and functional component via abundant physical and chemical route. With the unique structure and excellent performance, 3D graphene-based composites show great potential in energy storage, environmental protection, sensor, etc. This article reviews recent progress in preparation and application of 3D graphene-based composites, involving the 3D graphene/polymer composites system and the 3D graphene/inorganic nano composites system. 3D assembly methods of the two systems are summarized, and the structural features of the composites are analyzed. The application progress of 3D graphene-based composites is briefly introduced. Finally, the development prospect of 3D structure design and diverse applications in the future are also proposed.
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2017, Vol. 31 
