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《材料导报》期刊社  2017, Vol. 31 Issue (15): 10-17    https://doi.org/10.11896/j.issn.1005-023X.2017.015.002
  材料综述 |
阳离子部分取代Cu2ZnSnS4的研究进展*
甘国友1,2, 邹屏翰1,2, 沈韬1,2, 孙淑红1,2, 朱艳1,2
1 昆明理工大学材料科学与工程学院,昆明 650093;
2 云南省新材料制备与加工重点实验室,昆明650093;
Research Progress of Partial Substitution of Cation in Cu2ZnSnS4
GAN Guoyou1,2, ZOU Pinghan1,2, SHEN Tao1,2, SUN Shuhong1,2, ZHU Yan1,2
1 Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093;
2 Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650093;
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摘要 P型半导体Cu2ZnSnS4(CZTS)由于具有最佳的直接带隙(1.0～1.5 eV)、高的光吸收系数(超过104 cm-1)以及丰富、无毒的元素组成,使其成为商业化低成本太阳能电池最有希望的候选材料之一。然而,材料本身的一些缺陷制约了CZTS薄膜太阳能电池效率的提高。为了提高CZTS薄膜太阳能电池的效率,研究者们使用其他阳离子部分取代Cu、Zn或Sn来改善CZTS的缺陷。从CZTS的3种不同取代位置出发,综述了近年来各种阳离子部分取代CZTS的研究进展,同时对阳离子部分取代CZTS材料的发展前景进行了展望。
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甘国友
邹屏翰
沈韬
孙淑红
朱艳
关键词:  阳离子取代  Cu2ZnSnS4  铜锌锡硫太阳能电池    
Abstract: Cu2ZnSnS4 (CZTS), a p-type semiconductor, is one of the most promising candidates for application in low-cost solar cells, owing to its optimal direct band gap (ca. ～1.0-1.5 eV), high absorption coefficient (over 104 cm-1) in the visible wavelength region, as well as its composition of naturally abundant and nontoxic elements. However, the intrinsic limitations of CZTS, such as secondary phases, antisite defects, carrier lifetime,etc, hinder the improvement of the efficiency of CZTS thin-film solar cell. In order to enhance the efficiency of CZTS thin-film solar cell, researchers have used partial substitution of Cu, Zn or Sn by other ca-tions to improve the defects of CZTS. In this paper, the progress of partially substituted CZTS in recent years is reviewed from three different substitution sites for CZTS. At the same time, the development prospect of partially substituted CZTS is discussed.
Key words:  cation substitution    Cu2ZnSnS4    CZTS solar cell
               出版日期:  2017-08-10      发布日期:  2018-05-04
ZTFLH:  TK02  
基金资助: *国家自然科学基金(61302042;61671225);昆明理工大学材料科学与工程学院拔尖人才项目(2015-2017);云南省新材料制备与加工重点实验室开放基金(2015)
作者简介:  甘国友:男,1965年生,博士,教授,博士研究生导师,研究方向为多功能电子陶瓷材料、半导体薄膜及器件开发、特种粉体材料制备与技术 E-mail:ganguoyou@kmust.edu.cn 沈韬:通讯作者,男,1984年生,博士,教授,博士研究生导师,研究方向为复合材料电学性能、纳米功能材料、材料无损检测 E-mail:shentao@kmust.edu.cn
引用本文:    
甘国友, 邹屏翰, 沈韬, 孙淑红, 朱艳. 阳离子部分取代Cu2ZnSnS4的研究进展*[J]. 《材料导报》期刊社, 2017, 31(15): 10-17.
GAN Guoyou, ZOU Pinghan, SHEN Tao, SUN Shuhong, ZHU Yan. Research Progress of Partial Substitution of Cation in Cu2ZnSnS4. Materials Reports, 2017, 31(15): 10-17.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.015.002  或          http://www.mater-rep.com/CN/Y2017/V31/I15/10
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