Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (14): 1-3    https://doi.org/10.11896/j.issn.1005-023X.2017.014.001
  研究快报 |
用LiAlH4一步还原白炭黑制取多孔硅的研究*
汪徐春, 张雪梅, 叶祥桔, 陈俊明, 过家好, 张婷, 毛杰, 陈忠平
安徽科技学院化学与材料工程学院, 蚌埠 233000;
Preparation of Porous Silicon by One-step Reduction of Silica with LiAlH4
WANG Xuchun, ZHANG Xuemei, YE Xiangjie, CHEN Junming, GUO Jiahao, ZHANG Ting, MAO Jie, CHEN Zhongping
College of Chemistry and Material Engineering, University of Science and Technology of Anhui, Bengbu 233000;
下载:  全 文 ( PDF ) ( 1419KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 多孔硅因其独特高效的光电效应而日益成为国内外研究的热点。在温度为450 ℃和500 ℃的条件下,采用LiAlH4热还原白炭黑(微米或纳米级二氧化硅)一步制得多孔硅,并利用XRD、红外光谱、扫描电镜、固体发射光谱等对实验产物进行了表征和分析。所提出的方法既绿色环保,又经济实惠,具有潜在的应用和推广价值。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
汪徐春
张雪梅
叶祥桔
陈俊明
过家好
张婷
毛杰
陈忠平
关键词:  氢化锂铝  一步还原  多孔硅    
Abstract: Porous silicon is becoming a hot research topic both at home and abroad because of its unique and efficient photoelectric effect.The porous silicon was prepared by thermal reduction of silica (micro- or nano-silica) at a temperature of 450 ℃ and 500 ℃ by one-step reacting with LiAlH4.The products were characterized and analyzed by XRD, IR, SEM and SPEF. This experimental method is green and environmentally friendly which has potential value of application.
Key words:  lithium aluminum hydride    one-step reduction    porous silicon
               出版日期:  2017-07-25      发布日期:  2018-05-04
ZTFLH:  TB321  
  O649.4  
基金资助: *国家自然科学基金(21603002);安徽省人才基金(gxfxZD2016176);安徽省教育厅自然科学重点基金(KJ2016A171;KJ2016A184);材料科学与工程重点学科(AKZDXK2015A01)
作者简介:  汪徐春:男,1970年生,博士,教授,研究方向为功能材料 E-mail:xuchun.wang@163.com;wangxc@ahstu.edu.cn
引用本文:    
汪徐春, 张雪梅, 叶祥桔, 陈俊明, 过家好, 张婷, 毛杰, 陈忠平. 用LiAlH4一步还原白炭黑制取多孔硅的研究*[J]. 《材料导报》期刊社, 2017, 31(14): 1-3.
WANG Xuchun, ZHANG Xuemei, YE Xiangjie, CHEN Junming, GUO Jiahao, ZHANG Ting, MAO Jie, CHEN Zhongping. Preparation of Porous Silicon by One-step Reduction of Silica with LiAlH4. Materials Reports, 2017, 31(14): 1-3.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.014.001  或          http://www.mater-rep.com/CN/Y2017/V31/I14/1
1 Zhou Huang. Problems on high purity silicon industry development in our country[J]. Energy China,2008,30(1):5(in Chinese).
周篁. 关于我国高纯硅产业发展问题[J].中国能源,2008,30(1):5.
2 Canhan L T. Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers[J]. Appl Phys Lett,1990,57(10):1046.
3 Cullis A C, Canhan L T. Visible light emission due to quantum size effects in highly porous crystalline silicon[J]. Nature,1991,353:335.
4 Wei J, Buriak J M, Siuzdak G. Desorption-ionization mass spectrometry on porous silicon[J]. Nature,1999,399(6733):243.
5 Fan S S, Chapline M C, Franklin N R, et al. Self-oriented regular arrays of carbon nanotubes and their field emission properties[J]. Science,1999,283:512.
6 Bao Ximao. Visible light luminescent porous silicon [J]. Progress Phys,1993,13(1):280(in Chinese).
鲍希茂. 发光多孔硅[J]. 物理学进展,1993,13(1):280.
7 Cullis A C, Canhan L T, Loni A, et al. Progress towards silicon optoelectronics using porous silicon technology[J].Appl Surf Sci,1996,102:436.
8 Hirschman K D, Tsybeskov L, Duttagupta S P, et al. Silicon-based visible light-emitting devices integrated into microelectronic circuits[J]. Nature, 1996,384:338.
9 Xu Gaobin, Lu Yi, Chen Xing, et al. Study on controllable preparation of nanometer porous silicon[J].J Electron Measurement Instrumentation,2014,28(12):1308(in Chinese).
许高斌, 卢翌, 陈兴, 等. 纳米多孔硅可控制备研究[J]. 电子测量与仪器学报,2014,28(12):1308.
10 Zhang Lizhu, Duan Jiadi, Zhang Borui, et al. Photoluminescence of silicon quantum wire array fabricated by electrolytic etching[J]. Chin J Semiconductors,1992,13(3):193(in Chinese).
张丽珠, 段家低, 张伯蕊, 等. 氢氟酸电解腐蚀硅制备的量子线阵的光致发光[J]. 半导体学报,1992,13(3):193.
11 Ter L M, Blackwood D J, et al. Characterization of the illuminated silicon-electrolyte interface by fourier-transform infrared spectroscopy[J]. Phys Rev Lett,1989,62:308.
12 刘小兵, 史向华. 多孔硅与全硅基纳米薄膜发光理论及应用[M]. 长沙:国防科技大学出版社,2002.
13 Zou Jun, Peng Guanliang, Chen Junhua, et al. Annealing study of γ-LiAlO2 crystal grown by temperature gradient technique [J]. J Synthetic Crystals,2004,33(6):923(in Chinese).
邹军,彭观良,陈俊华,等. γ-LiAlO2晶体的退火研究[J]. 人工晶体学报,2004,33(6):923.
14 Teo B K, Sun X H. Silicon-based low-dimensional nanomaterials and nanodevices[J]. Chem Rev,2007,107:1454.
[1] 胡厅, 万红, 华叶, 龚瑾瑜, 陈兴宇. 石墨表面TiC梯度涂层的制备及结构调制[J]. 材料导报, 2019, 33(z1): 74-77.
[2] 杨飞跃, 赵爽, 陈国兵, 陈俊, 杨自春. Si3N4泡沫陶瓷的制备过程影响因素及复合化研究进展[J]. 材料导报, 2019, 33(z1): 178-183.
[3] 叶凯, 梁风, 姚耀春, 马文会, 杨斌, 戴永年. 直流电弧等离子体法制备纳米材料的研究进展[J]. 材料导报, 2019, 33(7): 1089-1098.
[4] 王译文, 王海斗, 马国政, 陈书赢, 何鹏飞, 丁述宇. Ti4O7功能陶瓷材料研究与应用现状[J]. 材料导报, 2019, 33(1): 143-151.
[5] 王俊杰, 房晶瑞, 汪澜. 水泥生产全过程硫循环机制的研究进展[J]. 材料导报, 2018, 32(23): 4160-4169.
[6] 王顺风, 马雪, 张祖华, 王爱国, 李亚林. 粉煤灰-偏高岭土基地质聚合物的孔结构及抗压强度[J]. 材料导报, 2018, 32(16): 2757-2762.
[7] 李延军, 刘冬华, 张电, 马昱昭. 含h-BN复相陶瓷制备及性能研究进展[J]. 材料导报, 2018, 32(15): 2609-2617.
[8] 李之锋, 罗垂意, 王春香, 钟盛文, 张骞. 无钴镍基正极材料LiNi0.7Mn0.3O2 氟掺杂改性研究[J]. 《材料导报》期刊社, 2018, 32(14): 2329-2334.
[9] 吴健, 关庆丰, 蔡杰, 吕鹏, 张从林, 李晨. 脉冲电子束作用下热障涂层微观结构及热循环性能[J]. 《材料导报》期刊社, 2018, 32(13): 2202-2207.
[10] 秦晓素,黄洁,雷云,杨泽斌,陈庆华,颜廷亭. 明胶/掺锶β-磷酸三钙/硫酸钙复合多孔支架的制备与性能[J]. 《材料导报》期刊社, 2018, 32(12): 1967-1972.
[11] 毕玉水. 时间控制/pH依赖型盐酸黄连素结肠给药系统的控释性能[J]. 《材料导报》期刊社, 2018, 32(12): 1973-1977.
[12] 贺春林,高建君,王苓飞,马国峰,刘岩,王建明. N2流量对反应共溅射TiN/Ni纳米复合膜结构和结合强度的影响[J]. 《材料导报》期刊社, 2018, 32(12): 2038-2042.
[13] 詹伟涛,贺建雄,王艺臻,姜宏. 羟基含量对全氧燃烧浮法玻璃结构弛豫的影响[J]. 《材料导报》期刊社, 2018, 32(12): 2062-2065.
[14] 袁琦, 茶丽梅, 明文全, 杨修波, 李石勇, 韩俊峰. 硒化温度对CIGS/Mo界面微观结构和化学成分的影响[J]. 《材料导报》期刊社, 2018, 32(11): 1787-1790.
[15] 苏文佳, 牛文清, 齐小方, 李琛, 王军锋. 定向凝固法多晶硅杂质控制数值模拟概述[J]. 《材料导报》期刊社, 2018, 32(11): 1795-1805.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed