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《材料导报》期刊社  2017, Vol. 31 Issue (12): 35-38    https://doi.org/10.11896/j.issn.1005-023X.2017.012.008
  材料研究 |
CrNi3MoVA钢表面电火花沉积W-Ni-Fe-Co涂层的摩擦磨损性能*
杨君宝1, 郭秋萍2, 赵博远3, 金浩1,4, 郭策安1, 张健1
1 沈阳理工大学装备工程学院, 沈阳 110159;
2 驻474军事代表室, 抚顺 113003;
3 中国人民解放军65186部队, 铁岭 112609;
4 沈阳工业大学材料科学与工程学院, 沈阳 110870
Friction and Wear Performance of W-Ni-Fe-Co Coating Electrospark Deposited on CrNi3MoVA Steel
YANG Junbao1, GUO Qiuping2, ZHAO Boyuan3, JIN Hao1,4, GUO Ce’an1, ZHANG Jian1
1 School of Equipment Engineering, Shenyang Ligong University, Shenyang 110159;
2 Department of Military Representatives in 474 Factory, Fushun 113003;
3 65186 PLA Troops, Tieling 112609;
4 School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870
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摘要 为进一步拓展火炮身管内膛强化手段,采用粉末冶金技术制备了W-Ni-Fe-Co合金,利用电火花表面沉积技术在CrNi3MoVA钢表面沉积了W-Ni-Fe-Co涂层,同时利用电镀技术在CrNi3MoVA钢表面制备了硬Cr涂层与之进行比较,用纳米压痕仪和摩擦磨损试验机研究了涂层的摩擦磨损性能,并利用XRD、SEM和EDS研究了沉积态和磨损后涂层的相结构、形貌及成分。结果表明电火花沉积W-Ni-Fe-Co涂层由α-W、γ-Fe和NiWO4组成,α-W在涂层中呈白亮带分布;W-Ni-Fe-Co涂层的硬度较电镀硬Cr涂层降低了18%,弹性模量较电镀硬Cr涂层提高了4%;W-Ni-Fe-Co涂层的磨损机制为轻微的粘着磨损,而电镀硬Cr涂层为严重的粘着磨损;CrNi3MoVA钢表面沉积W-Ni-Fe-Co涂层较电镀硬Cr涂层具有明显的减摩耐磨效果,随着摩擦速度的增加,W-Ni-Fe-Co涂层的摩擦系数降低,其原因是磨损表面氧化加剧,氧化物的自润滑作用加大。
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杨君宝
郭秋萍
赵博远
金浩
郭策安
张健
关键词:  CrNi3MoVA钢  W-Ni-Fe-Co涂层  电镀硬Cr涂层  电火花沉积  摩擦磨损    
Abstract: In order to further expand the route to harden gun bore, a W-Ni-Fe-Co alloy, prepared by powder metallurgy technology, was used as electrode to electrospark deposit on a CrNi3MoVA steel substrate. Meanwhile, a hard chromium coating was also plated on a CrNi3MoVA steel substrate for comparison. The performance of friction and wear of both coatings was tested by nanoindentor and friction and wear testing machine. Moreover, the phases, morphology and compositions of the deposited and worn coatings were analyzed by XRD, SEM and EDS. The results showed that the W-Ni-Fe-Co coating is composed of α-W distributed as bright band, γ-Fe and NiWO4. The hardness of the W-Ni-Fe-Co coating reduced 18% than that of the hard chromium coating whilst the elasticity modulus increased 4%. The wear mechanism of the W-Ni-Fe-Co coating is characterized as slight adherent wear while that of the hard chromium coating is severe one. In contrast to the hard chromium coating, the W-Ni-Fe-Co coating electrospark deposited on the CrNi3MoVA steel has an obvious function of antifriction and wear resistance, and what′s more, the friction coefficient is reducing with the increase of the friction velocity due to the enhancement effect of oxide self-lubricating with the aggravation of the worn surface.
Key words:  CrNi3MoVA steel    W-Ni-Fe-Co coating    electroplated hard chromium coating    electrospark deposition    friction and wear
               出版日期:  2017-06-25      发布日期:  2018-05-08
ZTFLH:  TB304  
  TB35  
基金资助: *辽宁省教育厅重点实验室基础研究项目(LZ2014013);沈阳理工大学辽宁省兵器科学与技术重点实验室开放基金(4771004kfs25)
通讯作者:  郭策安:通讯作者,男,1979年生,博士,主要从事腐蚀、磨损与表面技术研究 E-mail:373055507@qq.com   
作者简介:  杨君宝:男,1977年生,博士,工程师,主要从事兵器新材料新工艺研究 E-mail:ligong6094@126.com
引用本文:    
杨君宝, 郭秋萍, 赵博远, 金浩, 郭策安, 张健. CrNi3MoVA钢表面电火花沉积W-Ni-Fe-Co涂层的摩擦磨损性能*[J]. 《材料导报》期刊社, 2017, 31(12): 35-38.
YANG Junbao, GUO Qiuping, ZHAO Boyuan, JIN Hao, GUO Ce’an, ZHANG Jian. Friction and Wear Performance of W-Ni-Fe-Co Coating Electrospark Deposited on CrNi3MoVA Steel. Materials Reports, 2017, 31(12): 35-38.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.012.008  或          http://www.mater-rep.com/CN/Y2017/V31/I12/35
1 Zhang Jian, Guo Cean, Zhang Gang, et al. Performance of arc-ion plating Ti0.7Al0.3N coatings on PCrNi3MoVA steel[J]. Acta Armamentarii,2011,32(6):697(in Chinese).
张健, 郭策安, 张罡, 等. PCrNi3MoVA钢表面电弧离子镀Ti0.7-Al0.3N涂层的性能研究[J]. 兵工学报,2011,32(6):697.
2 Chen Yongcai, Song Qiuzhi, Wang Jianzhong. New technologies to extend the erosion life of gun barrel[J]. Acta Armamentarii,2006,27(2):330(in Chinese).
陈永才, 宋遒志, 王建中. 国内外火炮身管延寿技术研究进展 [J]. 兵工学报,2006,27(2):330.
3 Sopok S,Rickard C,Dunn S. Thermal-chemical-mechanical gun bore erosion of an advanced artillery system part one: Theories and me-chanisms[J]. Wear,2005,258:659.
4 Matson D W, McClanahan E D, Rice J P, et al. Effect of sputtering parameters on Ta coatings for gun bore applications [J]. Surf Coat Technol,2000,133-134:411.
5 Warnecke C. Method of internally coating a weapon barrel by a plasma flame:US, 6511710[P].2003-01.
6 Victor A, Andrew S. Method for making a high tem perature, high pressure, erosion and corrosion resistant composite structure:US,5935351[P].1999-08.
7 Li H X, Chen G N, Zhang G X, et al. Characteristics of the interface of a laser-quenched steel substrate and chromium electroplate [J]. Surf Coat Technol,2006,201(3-4):902.
8 Xie Y J, Wao M C. Isothermal oxidation behavior of electrospark deposited MCrAlX-type coatings on a Ni-based superalloy [J]. J Alloys Compd,2009,480:454.
9 Zhang Jian, Wang Yuanchao, Guo Cean, et al. Isothermal oxidation behavior of electrospark deposited NiCrAlY coatings on gun steel at 850 ℃ [J]. J Northeastern University: Nat Sci,2014,35(S2):213(in Chinese).
张健, 王远超, 郭策安, 等. 炮钢表面电火花沉积NiCrAlY涂层850 ℃恒温氧化行为 [J]. 东北大学学报: 自然科学版,2014,35(S2):213.
10 You Guoqiang, Chen Yong, Zhang Juncheng, et al. Research and application status of pulsed air arc deposition [J]. Mater Rev: Rev,2011,25(11):119(in Chinese).
游国强, 陈勇, 张均成,等. 电火花堆焊技术的研究与应用现状 [J]. 材料导报: 综述篇, 2011,25(11):119.
11 Tang Jingming. Microstructures and wear resistance of the TiC-TiB2 composite coating deposited by electrical discharge hardening [J]. Mater Rev: Res,2012,26(7):115(in Chinese).
汤精明. TiC-TiB2电火花复合强化层组织与耐磨性 [J]. 材料导报: 研究篇,2012,26(7):115.
12 Hong X, Tan Y F, Wang X L, et al. Effects of nitrogen flux on microstructure and tribological properties of in-situ TiN coatings depo-sited on TC11 titanium alloy by electrospark deposition [J]. Trans Nonferrous Met Soc China,2015,25(10):3329.
13 Cao T, Lei S, Zhang M. The friction and wear behavior of Cu/Cu-MoS2 self-lubricating coating prepared by electrospark deposition[J]. Surf Coat Technol,2015,270:24.
14 Hong X, Tan Y, Zhou C, et al. Microstructure and tribological properties of Zr-based amorphous-nanocrystalline coatings deposited on the surface of titanium alloys by electrospark deposition [J]. Appl Surf Sci,2015,356:1244.
15 Wang X R, Wang Z Q, He P, et al. Microstructure and wear pro-perties of CuNiSiTiZr high-entropy alloy coatings on TC11 titanium alloy produced by electrospark computer numerical control deposition process [J]. Surf Coat Technol,2015,283:156.
16 Ma Yunzhu, Liu Wensheng, et al. Effect of minor Co on microstructure and properties of 93W-4.9Ni-2.1Fe alloys[J]. Rare Met Mater Eng,2008,37(10):1804(in Chinese).
马运柱, 刘文胜, 等. 元素Co对93W-4.9Ni-2.1Fe合金微观组织和性能的影响 [J]. 稀有金属材料与工程,2008,37(10):1804.
17 Chen J M, Hou G, Chen J, et al. Composition versus friction and wear behavior of plasma sprayed WC-(W,Cr)2C-Ni/Ag/BaF2-CaF2 self-lubricating composite coatings for use up to 600 ℃ [J]. Appl Surf Sci,2012,261:584.
18 Ipaz L, et al. Improvement of mechanical and tribological properties in steel surfaces by using titanium-aluminum/titanium-aluminum nitride multilayered system [J]. Appl Surf Sci,2012,258(8):3805.
19 Archard J F. Contact and rubbing of flat surfaces [J]. J Appl Phys,1953,24:981.
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