Please wait a minute...
材料导报  2017, Vol. 31 Issue (1): 72-76    https://doi.org/10.11896/j.issn.1005-023X.2017.01.009
  材料综述 |
外援型自修复体系及其在环氧基复合材料中的应用
郭亚昆,邹东利,赵鹏翔,徐对功,仲敬荣,杨晓娇,帅茂兵
中国工程物理研究院材料研究所,江油 621908
External Self-healing Systems and Their Application in Epoxy Polymers
GUO Yakun, ZOU Dongli, ZHAO Pengxiang, XU Duigong, ZHONG Jingrong, YANG Xiaojiao, SHUAI Maobing
Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908
下载:  全 文 ( PDF ) ( 1300KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 聚合物基自修复材料是近年来国内外的研究热点。根据自修复过程是否需要外加修复剂,聚合物基复合材料自修复方法主要分为外援型自修复和本征型自修复。外援型自修复体系主要包括双环戊二烯修复体系、环氧基修复体系、硫醇基修复体系、甲基丙烯酸缩水甘油酯修复体系、马来酰亚胺修复体系等。着重介绍了这几种自修复体系及其在环氧基复合材料中的应用,并展望了外援型自修复体系在聚合物基复合材料的应用前景及发展方向。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
郭亚昆
邹东利
赵鹏翔
徐对功
仲敬荣
杨晓娇
帅茂兵
关键词:  外援型自修复  环氧复合材料  自修复体系  修复剂    
Abstract: Self-healing polymers have attracted lots of attentions and have been extensively studied recently. Healing method includes external self-healing and intrinsic self-healing according to if healing agent is required in the healing process. External self-healing systems include dicyclopentadiene-based healing system, epoxy-based healing system, thiol-based healing system, glycidylmethacrylate-based healing system, maleimide-based healing system and so on. This review attempts to introduce the application and progress of external self-healing systems in epoxy polymer and discuss the future development direction.
Key words:  external self-healing    epoxy polymer    self-healing systems    healing agent
               出版日期:  2017-01-10      发布日期:  2018-05-02
ZTFLH:  TB324  
  O63  
基金资助: 国家自然科学基金(51573172;11405149;51401187);中国工程物理研究院材料研究所所长基金重点项目(SJZ201506)
作者简介:  郭亚昆:女,1981年生,博士研究生,主要从事高分子材料研究 E-mail:yakunguo@126.com 帅茂兵:通讯作者,男,研究员,主要从事高分子材料合成及性能方面的研究 E-mail:shuaimaobing@caep.cn
引用本文:    
郭亚昆, 邹东利, 赵鹏翔, 徐对功, 仲敬荣, 杨晓娇, 帅茂兵. 外援型自修复体系及其在环氧基复合材料中的应用[J]. 材料导报, 2017, 31(1): 72-76.
GUO Yakun, ZOU Dongli, ZHAO Pengxiang, XU Duigong, ZHONG Jingrong, YANG Xiaojiao, SHUAI Maobing. External Self-healing Systems and Their Application in Epoxy Polymers. Materials Reports, 2017, 31(1): 72-76.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.01.009  或          http://www.mater-rep.com/CN/Y2017/V31/I1/72
1 陈平,刘胜平,王德中. 环氧树脂及其应用[M]. 北京:化学工业出版社,2011.
2 Zhang L, Li N, Zhang Y Y, et al. Research progress on high-functional epoxy resin matrix [J]. Mater Rev,2013,27(S2):242(in Chinese).
张丽,李楠,张媛媛,等.高性能环氧树脂基体的研究进展[J].材料导报,2013,27(专辑22):242.
3 Wu D Y, Meure S, Solomon D. Self-healing polymeric materials: A review of recent developments [J]. Prog Polym Sci,2008,33(5):479.
4 Dry C M, Sottos N R. Passive smart self-repair in polymer matrix composite materials [C]// Conference on Recent Advances in Adaptive and Sensory Materials and their Applications. Virginia, USA,1992:438.
5 White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites [J]. Nature,2001,409(6822):794.
6 Blaiszik B J, Kramer S L B, Olugebefola S C, et al. Self-healing polymers and composites [J]. Annual Rev Mater Res,2010,40:179.
7 Li T T, Wang R, Liu X. Current research on composites self-healed by microcapsules [J]. Mater Rev:Rev,2010,24(9):57(in Chinese).
李婷婷,王瑞,刘星.微胶囊自修复复合材料的研究进展[J]. 材料导报:综述篇,2010,24(9):57.
8 Wang M C, Zhu H R. Progress in the self-healing mechanisms of polymer materials [J]. Mater Rev:Rev,2012,26(6):89(in Chinese).
王明存, 朱海荣.高分子材料自修复机理的研究进展[]J.材料导报:综述篇,2012,26(6):89.
9 Xander K D, Hillewaere F E, Du P. Fifteen chemistries for autonomous external self-healing polymers and composites [J]. Prog Polym Sci,2015,49:121.
10 Rule J D, Moore J S. ROMP reactivity of endo-and exo-dicyclopentadiene [J]. Macromolecules,2002,35(21):7878.
11 Sheng X, Kessler M R, Lee J K. The influence of cross-linking agents on ring-opening metathesis polymerized thermosets [J]. J Thermal Anal Calorimetry,2007,89(2):459.
12 Larin G E, Bernklau N, Kessler M R, et al. Rheokinetics of ring-opening metathesis polymerization of norbornene-based monomers intended for self-healing applications [J]. Polym Eng Sci,2006,46(12):1804.
13 Lee J K, Liu X, Yoon S H, et al. Thermal analysis of ring-opening metathesis polymerized healing agents [J]. J Polym Sci Part B,2007,45(14):1771.
14 Wilson G O, Caruso M M, Reimer N T, et al. Evaluation of ruthenium catalysts for ring-opening metathesis polymerization-based self-healing applications [J]. Chem Mater,2008,20(10):3288.
15 Jones A S, Rule J D, Moore J S, et al. Catalyst morpholgy and dissolution kinetics of self-healing polymers [J]. Chem Mater,2006,18(5):1312.
16 Rule J D, Brown E N, Sottos N R, et al. Wax-protected catalyst microspheres for efficient self-healing materials [J]. Adv Mater,2005,17(2):205.
17 Jackson A C, Bartelt J A, Marczewski K, et al. Silica-protected micron and submicron capsules and particles for self-healing at the microscale [J]. Macromolecular Rapid Commun,2011,32(1):82.
18 Brown E N, Kessler M R, Sottos N R, et al. In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene [J]. J Microencapsulation,2003,20(6):719.
19 Bielawski C W, Grubbs R H. Living ring-opening metathesis polymerization [J]. Prog Polym Sci,2007,32(1):1.
20 Toohey K S, Hansen C J, Lewis J A, et al. Delivery of two-part self-healing chemistry via microvascular networks [J]. Adv Funct Mater,2009,19(9):1399.
21 Toohey K S, Sottos N R, Lewis J A, et al. Self-healing materials with microvascular networks [J]. Nat Mater,2007,6(8):581.
22 Blaiszik B J, Baginska M, White S R, et al. Autonomic recovery of fiber/matrix interfacial bond strength in a model composite [J]. Adv Funct Mater,2010,20(20):3547.
23 Jin H, Miller G M, Sottos N R, et al. Fracture and fatigue response of a self-healing epoxy adhesive [J]. Polymer,2011,52(7):1628.
24 Yin T, Rong M Z, Zhang M Q, et al. Self-healing epoxy compo-sites-Preparation and effect of the healant consisting of microencapsulated epoxy and latent curing agent [J]. Compos Sci Technol,2007,67(2):201.
25 Yin T, Rong M Z, Wu J, et al. Healing of impact damage in woven glass fabric reinforced epoxy composites [J]. Composites Part A,2008,39(9):1479.
26 Rong M Z, Zhang M Q, Zhang W. A novel self-healing epoxy system with microencapsulated epoxy and imidazole curing agent [J]. Adv Compos Lett,2007,16(5):167.
27 Hart K R, Sottos N R, White S R. Repeatable self-healing of an epoxy matrix using imidazole initiated polymerization [J]. Polymer,2015,67:174.
28 Xiao D S, Yuan Y C, Rong M Z, et al. A facile strategy for prepa-ring self-healing polymer composites by incorporationof cationic catalyst-loaded vegetable fibers [J]. Adv Funct Mater,2009,19(14):2289.
29 Xiao D S, Yuan Y C, Rong M Z, et al. Self-healing epoxy based on cationic chain polymerization [J]. Polymer,2009,50(13):2967.
30 Ye X J, Zhang J L, Zhu Y, et al. Ultrafast self-healing of polymer toward strength restoration [J]. ACS Appl Mater Interfaces,2014,6(5):3661.
31 Ye X J, Song Y X, Zhu Y, et al. Self-healing epoxy with ultrafast and heat-resistant healing system processable at elevated temperature [J]. Compos Sci Technol,2014,104:40.
32 Caruso M M, Delafuente D A, Ho V, et al. Solvent-promoted self-healing epoxy materials [J]. Macromolecules,2007,40(25):8830.
33 Caruso M M, Blaiszik B J, White S R, et al. Full recovery of fracture toughness using a nontoxic solvent-based self-healing system[J]. Adv Funct Mater,2008,18(13):1898.
34 Caruso M M, Blaiszik B J, Jin H, et al. Robust, double-walled microcapsules for self-healing polymeric materials[J]. ACS Appl Mater Interfaces,2010,2(4):1195.
35 Jones A R, Cintora A, White S R, et al. Autonomic healing of carbon fiber/epoxy interfaces [J]. ACS Appl Mater Interfaces,2014,6(9):6033.
36 Williams H R, Trask R S, Bond I P. Self-healing sandwich panels: Restoration of compressive strength after impact [J]. Compos Sci Technol,2008,68:3171.
37 Hansen C J, Wu W, Toohey K S, et al. Self-healing materials with interpenetrating microvascular networks [J]. Adv Mater,2009,21(41):4143.
38 Norris C J, Meadway G J, O’Sullivan M J, et al. Self-healing fiber reinforced composites via a bioinspired vasculature [J]. Adv Funct Mater,2011,21(19):3624.
39 Jin H H, Mangun C L, Griffin A S, et al. Thermally stable autonomic healing in epoxy using a dual-microcapsule system [J]. Adv Mater,2014,26(2):282.
40 Liu D R, Gao G M, Liu Y, et al. The synthesis and performance study of epoxy acrylate microcapsule [J]. Mater Rev,2014,28(S1):268(in Chinese).
刘大锐,高桂梅,刘瑜,等. 环氧丙烯酸酯微胶囊的制备与性能研究[J]. 材料导报,2014,28(专辑23):268.
41 Zhang H, Yang J L. Development of self-healing polymers via amine-epoxy chemistry: Ⅱ. Systematic evaluation of self-healing performance [J]. Smart Mater Struct,2014,23(6):065004/1.
42 Yuan Y C, Rong M Z, Zhang M Q, et al. Self-healing polymeric materials using epoxy/mercaptan as the healant [J]. Macromolecules,2008,41(14):5197.
43 Yuan Y C, Rong M Z, Zhang M Q. Preparation and characterization of microencapsulated polythiol [J]. Polymer,2008,49(10):2531.
44 Yuan Y C, Ye X J, Rong M Z, et al. Self-healing epoxy composite with heat-resistant healant [J]. ACS Appl Mater Interfaces,2011,3(11):4487.
45 Hillewaere X K D, Teixeira R F A, Nguyen L T T, et al. Autonomous self-healing of epoxy thermosets with thiol-isocyanate chemistry [J]. Adv Funct Mater,2014,24(35):5575.
46 Meng L M, Yuan Y C, Rong M Z, et al. A dual mechanism single-component self-healing strategy for polymers [J]. J Mater Chem,2010,20(29):6030.
47 Peterson A M, Jensen R E, Palmese G R. Room-temperature hea-ling of a thermosetting polymer using the Diels-Alder reaction [J]. ACS Appl Mater Interfaces,2010,2(4):1141.
48 Pratama P A, Peterson A M, Palmese G R. Diffusion and reaction phenomena in solution-based healing of polymer coatings using the Diels-Alder reaction [J]. Macromolecular Chem Phys,2012,213(2):173.
49 Pratama P A, Peterson A M, Palmese G R. The role of maleimide structure in the healing of furan-functionalized epoxy amine thermosets [J]. Polym Chem,2013,4(18):5000.
50 Pratama P A, Sharifi M, Peterson A M, et al. Room temperature self-healing thermoset based on the Diels-Alder reaction[J]. ACS Appl Mater Interfaces,2013,5(23):12425.
51 Zhu D Y, Guo J W, Cao G S, et al. Thermo-moldable self-healing commodity plastics with heat resisting and oxygen-insensitive healant capable of room temperature redox cationic polymerization[J]. J Mater Chem A,2015,3(5):1858.
52 Li W L, Matthews C C, Yang K, et al. Autonomous indication of mechanical damage in polymeric coatings [J]. Adv Mater,2016,28(11):2189.
[1] 谢全灵,邵文尧,马寒骏,刘晨然,洪专. 基于二维石墨烯纳米材料优化高分子分离膜的研究进展[J]. 材料导报, 2019, 33(17): 2958-2965.
[2] 王忠辉, 辛勇. 高分子链运动对氧气扩散行为的影响[J]. 材料导报, 2019, 33(8): 1293-1297.
[3] 陈道鸽, 熊向源, 龚妍春, 李资玲, 李玉萍. 含Pluronic高分子纳米粒子在药物释放体系的研究现状[J]. 材料导报, 2019, 33(3): 517-521.
[4] 林琳, 陈景民, 王会, 李久盛, 陈晋阳, 曾祥琼. 皮肤敷料的研究进展[J]. 材料导报, 2019, 33(1): 65-72.
[5] 杨贺珍, 冉奋. 超级电容器电解质研究进展[J]. 材料导报, 2018, 32(21): 3697-3705.
[6] 王志芳,宣承楷,刘雪敏,施雪涛. 环糊精衍生物水凝胶材料的研究进展[J]. 材料导报, 2018, 32(19): 3456-3464.
[7] 董文举, 孔令斌, 康龙, 冉奋. 超级电容器电极材料及器件的柔性化与微型化[J]. 材料导报, 2018, 32(17): 2912-2919.
[8] 李超, 马成章, 黄绍军, 闵春刚, 黄秋玲, 孙晓东. 含1,3,4-噻二唑环聚合物的合成及应用研究进展[J]. 《材料导报》期刊社, 2018, 32(11): 1891-1902.
[9] 陈曼, 何明, 郭妍婷, 尹国强. 静电纺羽毛角蛋白/聚乙烯醇/聚氧化乙烯纳米纤维膜的交联改性及表征[J]. 《材料导报》期刊社, 2018, 32(8): 1218-1223.
[10] 李军辉, 廖至金, 李志君, 廖双泉, 于人同. 羧基官能化聚丁二烯:点击化学合成及对环氧树脂的固化机理[J]. 材料导报, 2018, 32(6): 983-986.
[11] 朱建勇, 何兆益. 沥青胶结料自愈合研究进展[J]. 《材料导报》期刊社, 2018, 32(5): 847-854.
[12] 吴亚鸽, 冉奋. 纤维素基多孔碳膜的制备及其电化学性能研究[J]. 《材料导报》期刊社, 2018, 32(5): 715-718.
[13] 张雪荣, 胡银春, 席少晖, 王兆伟, 战岩, 黄棣, 胡超凡, 魏延. 静电纺β-环糊精/石墨烯载银抗菌纤维膜的制备与表征[J]. 《材料导报》期刊社, 2018, 32(4): 545-548.
[14] 谭永涛, 孔令斌, 康龙, 冉奋. Nano-Au@PANI蛋黄空心结构电极材料的构筑及超级电容性能[J]. 《材料导报》期刊社, 2018, 32(1): 47-50.
[15] 王静,刘红科,刘平生,李利. 高强度水凝胶纳米复合材料的研究进展[J]. 《材料导报》期刊社, 2018, 32(1): 67-75.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed